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CAS: 3219-63-4
分子式: C4H12OSi
分子量: 104.22
沸点: 121℃(754
英文名称: 
trimethylsilanyl-methanol
hydroxymethyltrimethylsilane
(trimethylsilyl)-methano
(hydroxymethyl)trimethyl-silan
trimethylsilylmethanol
推荐供应商
货号品牌产品名称规格包装、参考价格
T865446MACKLIN三甲基硅基甲醇98%86元/1ml;   286元/5ml;   996元/25ml;   咨询
储存:室温
状态:无色到几乎无色澄清液体
T1250TCITrimethylsilylmethanol>97.0%(GC)895元/5ML;   3025元/25ML;   咨询

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C4H12OSi = 104.22
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN1731486
PubChem物质ID87577026
SDBS (AIST Spectral DB)18858
MDL编号MFCD00004596

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点121 ℃
闪点56 ℃
比重0.83
折射率1.42

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#PC4100000

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
L04251Alfa Aesar1-Trimethylsilylmethanol95%796元/1g;   3119元/5g;   咨询

应用
1-Trimethylsilylmethanol is used as nucleophile to resolve the racemate obtained from enantioselective esterification of naproxen (2-(6-methoxy-2-naphthyl) propionic acid) by lipases. It was also used as a nucleophilic hydroxymethylation agent.

备注
Store at 4?°C. Incompatible with oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00004596

EINECS
221-746-5

分子式
(CH3)3SiCH2OH

分子量
104.23

沸点
121-122°

闪点
31°(87°F)

密度
0.827

折射率
1.4190

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Fully miscible in water.

Beilstein
1731486

GHS危害和防范说明

GHS符号

Hazard Statements
H226
Flammable liquid and vapour.

Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10
Flammable.

RTECS
PC4100000

TSCA

S19675Fluorochem(Trimethylsilyl)methanol98%2024元/5g;   8030元/25g;   咨询

基本信息

CAS Number3219-63-4
MDL NumberMFCD00004596
Boiling Point121-122℃
Density0.826

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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