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CAS: 319-03-9
分子式: C8H3FO3
分子量: 166.11
沸点: 148℃(20
熔点: 75-78℃
中文名称: 
4-氟联苯二甲酸酸酐
4-氟酞酐
4-氟邻苯二甲酸酐
英文名称: 
4-Fluorobenzene-1,2-dicarboxylic anhydride
5-Fluoro-isobenzofuran-1,3-dione
1,3-Isobenzofurandione,5-fluoro-
5-fluoro-3-isobenzofurandione
4-fluorophthalic anhydride
推荐供应商
货号品牌产品名称规格包装、参考价格
F875607MACKLIN4-氟邻苯二甲酸酐≥95%29元/200mg;   65元/1g;   271元/5g;   1131元/25g;   咨询
储存:室温
状态:白色到非常淡黄色晶体或粉末
F0322TCI4-Fluorophthalic Anhydride>98.0%(GC)690元/5G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H3FO3 = 166.11
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN131281
PubChem物质ID87570096
SDBS (AIST Spectral DB)19324
MDL编号MFCD00191363

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Morpholine Method)min. 97.0 %
Melting point76.0 to 80.0 ℃

物性(参考值)

熔点79 ℃
沸点206 ℃/160 mmHg
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
B21352Alfa Aesar4-Fluorophthalic Anhydride98%1658元/5g;   咨询

应用
4-Fluorophthalic anhydride is used in the preparation of 5-fluoro-2-pyridin-3-ylmethyl-isoindole-1,3-dione by reacting with C-pyridin-3-yl-methylamine.

备注
Moisture sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00191363

分子式
C8H3FO3

分子量
166.11

熔点
74-79°

沸点
147-149°/20mm

密度
1.500

灵敏度
Moisture Sensitive. Ambient temperatures.

溶解性
Soluble in sodium hydroxide.

Beilstein
131281

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

641375Sigma-Aldrich4-Fluorophthalic Anhydride97%1006.23元/5 G;   3635.44元/25 G;   咨询

产品说明

一般描述

4-Fluorophthalic anhydride is a fluorinated building block commonly used in chemical synthesis for the preparation of polyimide, pesticides, herbicides, and fungicides. It can be synthesized by treating 4-chlorophthalic anhydride with potassium fluoride.

应用

4-Fluorophthalic anhydride can be used as a reactant to prepare:

  • 4-amino substituted phthalimides applicable as potential fluorescent probes and fluorescent bioactive compounds.
  • 4,4′-bis(4-fluorophthalimido)diphenyl ether monomer, which is used in the synthesis of cardo polymers via nucleophilic substitution polymerization reaction.
  • Asymmetric polyimides by a solution polycondensation reaction.

包装

5, 25 g in glass bottle

基本信息

经验(实验)分子式C8H3FO3
分子量166.11
MDL编号MFCD00191363
PubChem化学物质编号24883115
NACRESNA.22

产品性质

质量水平200
测定97%
mp75-79 ℃ (lit.)
SMILES stringFc1ccc2C(=O)OC(=O)c2c1
InChI1S/C8H3FO3/c9-4-1-2-5-6(3-4)8(11)12-7(5)10/h1-3H
InChI keyXVMKZAAFVWXIII-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H315 - H319 - H335
预防措施声明P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
006356Fluorochem4-Fluorophthalic Anhydride97%1276元/5g;   4510元/25g;   咨询

基本信息

CAS Number319-03-9
MDL NumberMFCD00191363
Melting Point75-79℃
Density1.55

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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