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CAS: 3011-34-5
分子式: C7H5NO4
分子量: 167.12
沸点: 275 °C at 760 mmHg
熔点: 139-144℃
中文名称: 
4-羟基-3-硝基苯甲醛
英文名称: 
4-Formyl-2-nitrophenol
4-Formyl-3-nitrophenol
4-hydroxy-3-nitrobenzaldehyde
性质描述: 黄色针状结晶。熔点144-145℃。溶于醇,微溶于水。
生产方法: 将24g对羟基苯甲醛悬浮于100ml冰醋酸中,在搅拌下滴加1h。冷却,过滤,滤饼用冰水洗涤,经乙醇重结晶,得成品20g,收率61%。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
H835495MACKLIN4-羟基-3-硝基苯甲醛97%42元/25g;   162元/100g;   708元/500g;   2761元/2.5kg;   展开
储存:室温,密封,干燥,避光
状态:浅黄色粉末
物化性质:溶于醇,微溶于水
折射率:1.6280
H0924TCI4-Hydroxy-3-nitrobenzaldehyde>97.0%(GC)190元/5G;   690元/25G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C7H5NO4 = 167.12
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN2047884
PubChem物质ID87571280
SDBS (AIST Spectral DB)13316
MDL编号MFCD00007117

技术规格

AppearanceLight yellow to Yellow to Orange powder to crystal
Purity(GC)min. 97.0 %
Melting point141.0 to 145.0 ℃

物性(参考值)

熔点143 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
528793J&K4-Hydroxy-3-nitrobenzaldehyde97%105元/5G;   219元/25G;   648元/100G;   展开

基本信息

分子式C7H5NO4
分子量167.12
熔点140-142
MDL编码MFCD00007117
Beilstein2047884
EINECS 编号221-141-6

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
A17972Alfa Aesar4-Hydroxy-3-nitrobenzaldehyde98%1139元/5g;   6560元/25g;   21690元/100g;   展开

基本信息

MDL
MFCD00007117

EINECS
221-141-6

分子式
C7H5NO4

分子量
167.12

熔点
140-144°

形态
Powder

Beilstein
2047884

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C16289Alfa Aesar4-Hydroxy-3-nitrobenzaldehyde97%1063元/5g;   3435元/25g;   展开

基本信息

Ref#
16289

MDL
7117

分子式
C7 H5 N O4

分子量
167.12

144320Sigma-Aldrich4-Hydroxy-3-nitrobenzaldehyde97%357.98元/5 G;   975.19元/25 G;   展开

产品说明

一般描述

4-Hydroxy-3-nitrobenzaldehyde reacts with 3-bromo­benzohydrazide in methanol to yield (E)-3-bromo-N′-(4-hydroxy-3-nitrobenzylidene)benzohydrazide.

应用

4-Hydroxy-3-nitrobenzaldehyde was used in the synthesis of:

  • 4-hydroxy-3-nitrocinnamic acid
  • solvated benzohydrazone derivatives: N′-(4-hydroxy-3-nitrobenzylidene)-3-methylbenzohydrazide-methanol-water

包装

5, 25 g in glass bottle

基本信息

线性分子式HOC6H3(NO2)CHO
分子量167.12
Beilstein2047884
EC 号221-141-6
MDL编号MFCD00007117
PubChem化学物质编号24848648

产品性质

质量水平100
测定97%
mp140-142 ℃ (lit.)
SMILES string[H]C(=O)c1ccc(O)c(c1)[N+]([O-])=O
InChI1S/C7H5NO4/c9-4-5-1-2-7(10)6(3-5)8(11)12/h1-4,10H
InChI keyYTHJCZRFJGXPTL-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
018721Fluorochem4-Hydroxy-3-nitrobenzaldehyde98%220元/1g;   264元/10g;   506元/25g;   1320元/100g;   展开

基本信息

CAS Number3011-34-5
MDL NumberMFCD00007117
Boiling Point295.67℃
Melting Point137-145℃
Density1.5216

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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