产品说明
应用
Boron tribromide dimethyl sulfide complex (BBr3S(CH3)2) can be used as a reagent:
- To prepare demethylated products from aryl methyl ethers by deprotection of methyl groups.
- To hydrolyze 1,3-methylenedioxole ring compounds to 1,2-dihydroxy compounds.
- To prepare benzyl S,S′-diphenyl acetal by reacting with phenylacetic acid and thexylphenylthioborane.
- To synthesize Baylis−Hillman adducts and α-halomethyl enones by the reaction between aldehydes and 3-buten-2-one.
Reactant for preparation of:
- Precursor of HIV protease inhibitor KNI 764 using cation-exchange resin mediated Mannich reaction
Reagent for:
包装
100 mL in Sure/Seal™
基本信息
| 线性分子式 | (CH3)2S·BBr3 |
| 分子量 | 312.66 |
| MDL编号 | MFCD00043296 |
| PubChem化学物质编号 | 24854866 |
| NACRES | NA.22 |
产品性质
| 形式 | liquid |
| 质量水平 | 100 |
| 浓度 | 1.0 M in methylene chloride |
| 密度 | 1.456 g/mL at 25 ℃ |
| SMILES string | C[S+](C)[B-](Br)(Br)Br |
| InChI | 1S/C2H6BBr3S/c1-7(2)3(4,5)6/h1-2H3 |
| InChI key | NCVLHAUANAMSTL-UHFFFAOYSA-N |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H314 - H336 - H351 |
| 预防措施声明 | P201 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P308 + P313 |
| 危险分类 | Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3 |
| 靶器官 | Central nervous system |
| 补充剂危害 | EUH014 |
| 储存分类代码 | 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
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