CAS 29934-17-6; 双(三环己基膦)二氯化钯; Dichlorobis(tricyclohexylphophine)palladium(II)

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货号

品牌

产品名称

规格

包装、参考价格

B823800

MACKLIN

双(三环己基膦基)二氯化钯(II)

97%

41元/200mg; 133元/1g; 661元/5g;

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储存：2~8℃,干燥,密封
状态：黄色粉末或晶体

B2055

TCI

Bis(tricyclohexylphosphine)palladium(II) Dichloride

>97.0%(T)

805元/1G; 2990元/5G;

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基本信息

纯度/分析方法	>97.0%(T)
分子式/分子量	C₃₆H₆₆Cl₂P₂Pd = 738.19
外观与形状(20℃)	固体
储存温度	<0℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,加热
Reaxys-RN	21356994
PubChem物质ID	87564929
MDL编号	MFCD00191830

技术规格

Appearance	Light orange to Yellow to Green powder to crystal
Purity(Argentometric Titration)	min. 97.0 %
Purity(Chelometric Titration)	min. 97.0 %

195061

J&K

Dichlorobis(tricyclohexylphosphine)palladium(II)

98%

352元/250MG; 944元/1G; 3515元/5G;

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基本信息

分子式	C₃₆H₆₆P₂·PdCl₂
分子量	738.18
熔点	270
MDL编码	MFCD00191830

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H316 H320 H335
防范说明	P280 P305+P351+P338
WGK	3
TSCA	否

535690

J&K

Dichlorobis(tricyclohexylphosphine)palladium(II)

14% 钯, Umicore制造

407元/250MG; 1341元/1G; 5354元/5G;

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基本信息

分子式	C₃₆H₆₆P₂·PdCl₂
分子量	738.18
熔点	270
MDL编码	MFCD00191830
Beilstein	21356994
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H316 H320 H335
防范说明	P280 P305+P351+P338
WGK	3
TSCA	否

46-0520

Strem

trans-Dichlorobis(tricyclohexylphosphine)palladium(II)

99%

690元/250mg; 1015元/1g; 4282元/5g;

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46-2040

Strem

trans-Dichlorobis(tricyclohexylphosphine)palladium(II)/potassium phosphate admixture

CatKit single-use vials - 6.62 wt% Pd complex

1260元/5×1vial; 5010元/25×1vial;

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Technical Note:

1. Convenient, pre weighed vial of palladium catalyst/base admixture useful for screening reactions. The vial contains 453mg of admixture, which will deliver 4 mole% of palladium catalyst and 2 equivalents of base, to a reaction using 1 mmole ofsubstrate.

044844

Alfa Aesar

Dichlorobis(tricyclohexylphosphine)palladium(II)

3974元/1g;

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应用
It is used as catalyst for C-C and C-N coupling reaction. It is used in the homogeneous carbonylation of chloroarenes under mild conditions.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Ensure good ventilation at the work place.

基本信息

MDL
MFCD00191830

分子式
C₃₆H₆₆Cl₂P₂Pd

分子量
738.18

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Moderately soluble in dichloromethane and chloroform. Sparingly soluble in benzene and toluene. Insoluble in water, alcohols, acetone, diethyl ether, and hexanes.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

403237

Sigma-Aldrich

Dichlorobis(tricyclohexylphosphine)palladium(II)

95%

1646.72元/1 G; 4609.52元/5 G;

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产品说明

一般描述

二氯双(三环己基膦)钯 (II) 被广泛用作各种碳-碳键和碳-杂原子键形成反应的催化剂前体。

应用

钯催化交叉偶联反应应用指南
用于C-C和C-N偶联反应的催化剂。

包装

1, 5 g in glass bottle

基本信息

线性分子式	[(C₆H₁₁)₃P]₂PdCl₂
分子量	738.18
MDL编号	MFCD00191830
PubChem化学物质编号	24864894
NACRES	NA.22

产品性质

质量水平	100
测定	95%
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
mp	270 ℃ (dec.) (lit.)
SMILES string	Cl[Pd]Cl.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6
InChI	1S/2C18H33P.2ClH.Pd/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h216-18H,1-15H2;2*1H;/q;;;;+2/p-2
InChI key	VUYVXCJTTQJVKJ-UHFFFAOYSA-L

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

048594

Fluorochem

Dichloro(tricyclohexylphosphine)palladium (II)

95%

1738元/1g; 4752元/5g;

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基本信息

CAS Number	29934-17-6
MDL Number	MFCD00191830

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .