| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| S818249 | MACKLIN | (1S,2S)-(-)-1, 2－二苯基－1, 2－乙二胺 | 98% | 36元/1g; 74元/5g; 364元/25g; 1190元/100g; | 咨询 |
储存：2~8°C 状态：白色到淡黄色固体 折射率：-103 ° (C=1, EtOH) |
| D2175 | TCI | (1S,2S)-(-)-1,2-Diphenylethylenediamine | >98.0%(GC)(T) | 515元/1G; 2085元/5G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC)(T) | | 分子式/分子量 | C14H16N2 = 212.30 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 2369988 | | PubChem物质ID | 87568615 | | MDL编号 | MFCD00082751 |
技术规格 | Appearance | White to Light yellow powder to crystal | | Purity(GC) | min. 98.0 % | | Purity(Nonaqueous Titration) | min. 98.0 % | | Melting point | 81.0 to 85.0 ℃ | | Specific rotation [a]20/D | -98.0 to -108.0 deg(C=1, EtOH) |
物性(参考值) | 熔点 | 83 ℃ | | 比旋光度 [α]D | -103° (C=1,EtOH) | | 水溶性 | 微溶 | | 溶解性(可溶于) | 甲苯,甲醇 |
安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 452067 | J&K | (1S,2S)-(-)-1,2-Diphenylethylenediamine | 99% | 60元/250mg; 173元/1G; 825元/5G; | 咨询 |
基本信息 | 分子式 | C14H16N2 | | 分子量 | 212.29 | | 熔点 | 83-85 | | 比旋光度([α]20D) | -106° to -102° (C=1.1, MeOH) | | MDL编码 | MFCD00082751 | | Beilstein | 3201645 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 07-0475 | Strem | (1S,2S)-(-)-1,2-Diphenylethylenediamine | min. 97% | 705元/500mg; 1440元/2g; 3885元/10g; | 咨询 |
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| L12968 | Alfa Aesar | (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine | 97% | 941元/250mg; 3924元/1g; | 咨询 |
应用
(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine solvation agent, For synthesis of enantiopure ethylenediamines by chirality transfer (condensation with diketones followed by reductive cleavage), Co-catalyst in the Ru catalyzed enantioselective hydrogenation of aromatic ketones, Versatile ligand for the formation of metal complexes.1 Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis 备注
Keep container tightly closed. Store in cool, dry conditions in well sealed containers. It is sensitive to air. 基本信息 MDL
MFCD00082751 分子式
C14H16N2 分子量
212.30 熔点
80-84° 灵敏度
Keep Cold. Air Sensitive. 形态
Crystalline powder 溶解性
Insoluble in water. Beilstein
3201645 GHS危害和防范说明 GHS符号
 Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician. 安全信息 危险等级
8 包装组
III 危险类别
34
Causes burns. 安全等级
26-36/37/39-45-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
 TSCA
否 |
| 364002 | Sigma-Aldrich | (1S,2S)-(-)-1,2-Diphenylethylenediamine | 97% | 729.55元/500 MG; | 咨询 |
产品说明 一般描述 1,2-二苯基乙二胺是一种手性分子，通常用作手性拆分剂和手性助剂前体。它还可用作NMR研究的手性溶剂化试剂。 包装 500 mg in glass bottle
无底玻璃瓶。内含物在插入的融合锥体内。 应用 形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的 tropocoronand。 基本信息 | 线性分子式 | [C6H5CH(NH2)-]2 | | 分子量 | 212.29 | | Beilstein | 3201645 | | MDL编号 | MFCD00082751 | | PubChem化学物质编号 | 24862409 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 97% | | 旋光性 | [α]20/D −102°, c = 1 in ethanol | | 光学纯度 | ee: 98% (GLC) | | mp | 83-85 ℃ (lit.) | | SMILES string | N[C@H]([C@@H](N)c1ccccc1)c2ccccc2 | | InChI | 1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m0/s1 | | InChI key | PONXTPCRRASWKW-KBPBESRZSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 011709 | Fluorochem | (1S,2S)-(-)-1,2-Diphenylethylenediamine | 98% | 264元/1g; 792元/5g; 1144元/10g; 2156元/25g; 6644元/100g; | 咨询 |
基本信息 | CAS Number | 29841-69-8 | | MDL Number | MFCD00082751 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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