[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 29263-94-3
关键词:       仅模糊查询
CAS: 29263-94-3
分子式: C8H13BrO4
分子量: 253.09
中文名称: 
2-溴代-2-甲基丙二酸二乙酯
2-溴-2-甲基丙二酸二乙酯
英文名称: 
2-Bromo-2-methylmalonic acid diethyl ester
2-(bromomethyl)-propanedioic acid diethyl ester
diethyl 2-bromo-2-methylmalonate
用途: 用作医药的原料和农药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
D838171MACKLIN2-溴代-2-甲基丙二酸二乙酯98%174元/25g;   688元/100g;   2985元/500g;   咨询
储存:室温,干燥
D4368TCIDiethyl 2-Bromo-2-methylmalonate>98.0%(GC)(T)715元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C8H13BrO4 = 253.09
外观与形状(20℃)液体
Reaxys-RN1779673
PubChem物质ID253659816
MDL编号MFCD00009125

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %
Purity(Argentometric Titration)min. 98.0 %

物性(参考值)

沸点59 ℃/0.2 mmHg
比重1.35
折射率1.45

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 II
监管条件代码(*)
L00575Alfa AesarDiethyl 2-Bromo-2-methylmalonate98%1008元/25g;   3770元/100g;   咨询

基本信息

MDL
MFCD00009125

EINECS
249-541-6

分子式
C8H13BrO4

分子量
253.10

沸点
105-106°/5mm

闪点
>110°(230°F)

密度
1.323

折射率
1.4490

灵敏度
Ambient temperatures.

Beilstein
1779673

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

139440Sigma-AldrichDiethyl 2-Bromo-2-methylmalonate98%1236.33元/25 G;   咨询

产品说明

一般描述

Diethyl 2-bromo-2-methylmalonate acts as initiator during the atom transfer radical polymerization of methyl methacrylate.

应用

Diethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.

包装

25 g in glass bottle

基本信息

线性分子式BrC(CH3)(CO2C2H5)2
分子量253.09
EC 号249-541-6
MDL编号MFCD00009125
PubChem化学物质编号24848412
NACRESNA.22

产品性质

质量水平100
测定98%
形式liquid
折射率n20/D 1.449 (lit.)
密度1.325 g/mL at 25 ℃ (lit.)
SMILES stringCCOC(=O)C(C)(Br)C(=O)OCC
InChI1S/C8H13BrO4/c1-4-12-6(10)8(3,9)7(11)13-5-2/h4-5H2,1-3H3
InChI keyCSLQAXTUGPUBCW-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
470917FluorochemDiethyl 2-Bromo-2-methylmalonate97%1254元/5g;   2288元/25g;   咨询

基本信息

CAS Number29263-94-3
MDL NumberMFCD00009125
Boiling Point59℃
Density1.35

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9