基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H314 H318 H400
防范说明	P273 P280 P303+P361+P353 P305+P351+P338 P310
UN号码	3260
危险分类	8
包装等级	III
WGK	3
TSCA	是

应用
Silver trifluoromethanesulfonate is useful in halide abstraction. It helps in activating sulphur protecting groups at the anomeric centres of carbohydrates in the presence of iodine. It is employed as a triflating agent in combination with Palladium compounds, as a catalyst for cross coupling reactions, and in several organic transformation reactions. Polyurethanes prepared from silver triflate exhibit high permeability and selectivity towards olefins in their separation from paraffin mixtures. Polyethylene oxide - silver triflate composites find application in humidity sensors.

备注
Stable. Light sensitive. Incompatible with strong acids and strong oxidizing agents. Trifluoromethanesulfonate is a weakly coordinating anion.

基本信息

MDL
MFCD00013226

EINECS
220-882-2

分子式
CAgF₃O₃S

分子量
256.93

熔点
356°

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water and also in most organic solvents.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318-H400
Causes severe skin burns and eye damage.Causes serious eye damage.Very toxic to aquatic life.

Precautionary Statements
P273-P280-P303+P361+P353-P305+P351+P338-P310
Avoid release to the environment.Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.

安全信息

危险类别
34-50
Causes burns.Very toxic to aquatic organisms.

安全等级
26-36/37/39-45-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
是

基本信息

Ref#
17520

MDL
MFCD00013226

EINECS
220-882-2

分子式
C Ag F3 O3 S

分子量
256.93

熔点
356°

形态
Powder

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
是

产品说明

应用

金催化剂— 21世纪的′淘金热′
三氟甲磺酸银是一种反应性三氟甲烷磺酸试剂，可作为可溶性银离子来源，用于亲电络合阳离子合成，促进傅-克烷基化、亲核烯烃环化和酯化反应。
它还可用于：

• 从仲磷酸盐和硫代磷酸盐获取烯烃。
• 用作在温和条件下醚化醇和伯烷基卤化物的试剂。
• 从氯铑配合物中制备用于乙炔加氢磷酸化的阳离子铑催化剂。
• 用作通过醛的硅氢加成，制备甲硅烷基醚的催化剂。

包装

1, 10, 25, 100 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H315 - H318
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P362 + P364
危险分类	Eye Dam. 1 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

应用

金催化剂— 21世纪的′淘金热′

• 三氟甲磺酸银 (AgOTf) 是一种将烷基、酰基和磺酰基卤化物转化为相应的三氟甲磺酸酯的反应性三氟甲磺酸酯。
• 它是一种高度合适的亲电试剂，可引发取代的 5-己烯-1-炔-3-醇的乙酰基氧-Cope 重排，合成相应的 α,δ-二乙基醛。
• 也可用于氨基烯酮的非对映选择性环化反应，其中非对映选择性取决于 Ag (I) 浓度。

包装

5 g in poly bottle
1 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H315 - H318
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P362 + P364
危险分类	Eye Dam. 1 - Skin Irrit. 2
储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

一般描述

已制备了单烯、二烯、三烯、单炔和二炔的三氟甲磺酸银p-络合物。它与2-氟-和3-氟-4-烷氧基噻唑反应，生成介晶复合物。 一氯化碘/ AgOTf构成了O糖苷合成的有效启动子系统。

应用

三氟甲磺酸银(AgOTf)可以在几种醇的糖基化过程中用作试剂。AgOTf与p-硝基苯磺酰氯的结合可以用作糖基化的活化剂。
可用于合成以下物质：

• 含胱氨酸肽
• 3-氨基烷基化吲哚
• 苯并 [ b ] 氧杂萘和 2 H -色烯类
• 多取代亚氨基咪唑嗪

其他说明

用于通过三氟甲磺酸盐对卤化物进行取代的试剂。；用于糖基卤化物糖基化的试剂；用于受保护硫醇脱保护的试剂

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H315 - H318
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P362 + P364
危险分类	Eye Dam. 1 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

分析说明

Assay (argentometric): ≥ 97.0 %
Identity (IR): passes test

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H315 - H318
预防措施声明	P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P362 + P364
危险分类	Eye Dam. 1 - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3

基本信息

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .