基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 : 吞咽有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

运输信息

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H226 H302 H315 H318 H335
防范说明	P261 P280 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	III
WGK	3
RTECS	XJ1290000
TSCA	是

应用
Thiazole is used as a flavoring agent and in the preparation of dyes and rubber accelerators. It serves as a component of the vitamin thiamine (B1). It acts as a protected formyl group used in natural product synthesis. It reacts with alkyl lithium and Grignard?’s reagent to prepare organometallic complexes. It is involved in the electrophilic aromatic substitution and nucleophilic aromatic substitution at C-5 and C-2 positions respectively. Further, it undergoes alkylation reaction to get thiazolium cation, which is used as a catalyst in the Stetter reaction and the Benzoin condensation. In addition to this, it is involved in the preparation of alagebrium.

备注
Air and light sensitive. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents and carbon dioxide.

基本信息

MDL
MFCD00005315

EINECS
206-021-3

分子式
C₃H₃NS

分子量
85.13

熔点
-33°

沸点
117-118°

闪点
22°(71°F)

密度
1.200

折射率
1.5390

灵敏度
Air Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Soluble in ethanol and ether. Slightly soluble in water.

Beilstein
103852

Merck
14,9307

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H302-H319
Highly flammable liquid and vapour.Harmful if swallowed.Causes serious eye irritation.

Precautionary Statements
P210-P261-P280f-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
3

包装组
III

危险类别
10-22-36
Flammable.Harmful if swallowed.Irritating to eyes.

安全等级
23-26-36-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XJ1290000

TSCA
是

基本信息

Ref#
16613

MDL
5315

分子式
C3 H3 N S

分子量
85.12

闪点
26

密度
1198

安全信息

危险等级
3

包装组
III

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H302
预防措施声明	P210 - P233 - P240 - P241 - P242 - P301 + P312
危险分类	Acute Tox. 4 Oral - Flam. Liq. 2
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	71.6 °F - closed cup
闪点(C)	22 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H302: Harmful if swallowed. H315: Causes skin irritation. H318: Causes serious eye damage. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use CO2 for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.