[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 27126-76-7
关键词:       仅模糊查询
CAS: 27126-76-7
分子式: CH3C6H4SO3I(OH)C6H5
分子量: 392.21
熔点: 131-137℃
英文名称: 
(hydroxy(tosyloxy)iodo)benzene
推荐供应商
货号品牌产品名称规格包装、参考价格
H810830MACKLIN羟基(甲苯磺酰氧代)碘苯97%30元/5g;   106元/25g;   339元/100g;   1468元/500g;   咨询
储存:2~8°C
状态:白色到黄色粉末或晶体
P1015TCI[Hydroxy(tosyloxy)iodo]benzene>97.0%(T)320元/5G;   1045元/25G;   咨询

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C13H13IO4S = 392.21
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解)
Reaxys-RN2150074
PubChem物质ID87575127
SDBS (AIST Spectral DB)18485
Merck Index (14)5321
MDL编号MFCD00011547

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(Neutralization titration)min. 97.0 %
Purity(Iodometric Titration)min. 97.0 %
Solubility in Methanolvery faint turbidity

物性(参考值)

熔点138 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
595536J&K[Hydroxy(tosyloxy)iodo]benzene98%156元/5G;   708元/25G;   咨询

基本信息

分子式C13H13IO4S
分子量392.21
熔点131-137
MDL编码MFCD00011547
Beilstein2150074
Merck14,5321

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
防范说明P305+P351+P338
WGK3
TSCA否
L15701Alfa AesarHydroxy(tosyloxy)iodobenzene97%684元/5g;   2195元/25g;   咨询

基本信息

MDL
MFCD00011547

EINECS
000-000-0

分子式
C13H13IO4S

分子量
392.22

熔点
131-136°

灵敏度
Light Sensitive. Ambient temperatures.

Beilstein
2150074

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
否

C38961Alfa Aesar[Hydroxy(tosyloxy)iodo]benzene97+%866元/5g;   2702元/25g;   咨询

基本信息

Ref#
38961

MDL
11547

分子式
C13 H13 I O4 S

分子量
392.21

301035Sigma-Aldrich[Hydroxy(tosyloxy)iodo]benzene96%359.85元/5 G;   1110.19元/25 G;   咨询

产品说明

应用

用作以下过程的反应物:

  • 无配体钯催化的 Heck 型偶联反应
  • 硫脲脱氢制备碳二亚胺
  • 醇、醛、胺氧化转化制备腈
  • 芳香族醛肟反应制备取代苯胺
  • 高烯丙基醇氧化环化合成四氢呋喃
  • β-羟基酮肟氧化 N-O 偶联制备异恶唑啉 N-氧化物
  • 氨肽酶抑制剂合成中的扩环反应
  • 酸性条件下的氧化和质子化反应

广泛用于合成各种有机化合物的氧化剂。

包装

5, 25 g in glass bottle

基本信息

线性分子式CH3C6H4SO3I(OH)C6H5
分子量392.21
Beilstein2150074
MDL编号MFCD00011547
PubChem化学物质编号24858159
NACRESNA.22

产品性质

质量水平200
测定96%
reaction suitabilityreagent type: oxidant
mp131-137 ℃ (lit.)
SMILES stringCc1ccc(cc1)S(=O)(=O)O[I](O)c2ccccc2
InChI1S/C13H13IO4S/c1-11-7-9-13(10-8-11)19(16,17)18-14(15)12-5-3-2-4-6-12/h2-10,15H,1H3
InChI keyLRIUKPUCKCECPT-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
068020FluorochemHydroxy{[(4-methylphenyl)sulfonyl]oxy}phenyliodine (HTIB)97%220元/1g;   220元/5g;   418元/10g;   792元/25g;   2376元/100g;   咨询

基本信息

CAS Number27126-76-7
MDL NumberMFCD00011547
Melting Point131-137℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9