| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| B802405 | MACKLIN | [双(三氟乙酰氧基)碘]苯 | 97% | 44元/5g; 99元/25g; 341元/100g; 1472元/500g; | 咨询 |
储存：2~8°C 状态：白色到淡黄色粉末,晶体和/或块状 |
| 516004 | J&K | [Bis(trifluoroacetoxy)iodo]benzene | 98% | 198元/10G; 690元/50G; | 咨询 |
基本信息 | 分子式 | C10H5F6IO4 | | 分子量 | 430.03 | | 熔点 | 121-125 | | MDL编码 | MFCD00009672 | | Beilstein | 764767 | | EINECS 编号 | 220-308-0 |
安全信息 | 图形或危害标志 |  | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
|
| L15141 | Alfa Aesar | [Bis(trifluoroacetoxy)iodo]benzene | 97% | 725元/5g; 2137元/25g; | 咨询 |
应用
[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride. 备注
Light and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases. 基本信息 MDL
MFCD00009672 EINECS
220-308-0 分子式
C10H5F6IO4 分子量
430.04 熔点
122-125° 灵敏度
Keep Cold. Moisture Sensitive. Light Sensitive. 形态
Crystalline powder 溶解性
Insoluble in water. Beilstein
764767 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| C21367 | Alfa Aesar | [Bis(trifluoroacetoxy)iodo]benzene | 98% | 964元/10g; 3081元/50g; | 咨询 |
基本信息 Ref#
21367 MDL
9672 分子式
C10 H5 F6 I O4 分子量
430.03 形态
White to pale yellow cryst powder |
| 232130 | Sigma-Aldrich | [Bis(trifluoroacetoxy)iodo]benzene | 97% | 667.54元/10 G; 2123.59元/50 G; | 咨询 |
产品说明 应用 反应物或试剂用于： - Pummerer 类反应
- 二甲氧基苄基醚的化学选择性脱保护
- 介导氧化环异构化
- 苯胺类的甲氧基化
在酸性条件下用于酮的直接 α-羟基化反应。也可作为 4-烷基酚的对氟化试剂，可在吡啶氢氟酸盐(产品目录号184225)存在的条件下合成 4-氟环己-2,5-二烯酮。 用于 N-酰腙经氧化反应生成 1,3,4-噁二唑的试剂。促进苯乙烯胺环化反应生成 N-烷基吲哚或 N-芳基吲哚。 包装 10, 50 g in glass bottle 基本信息 | 线性分子式 | (CF3CO2)2IC6H5 | | 分子量 | 430.04 | | Beilstein | 764767 | | EC 号 | 220-308-0 | | MDL编号 | MFCD00009672 | | PubChem化学物质编号 | 24853882 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 97% | | reaction suitability | reagent type: oxidant | | mp | 121-125 ℃ (lit.) | | SMILES string | FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1 | | InChI | 1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H | | InChI key | PEZNEXFPRSOYPL-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
|
| 15230 | Sigma-Aldrich | [Bis(trifluoroacetoxy)iodo]benzene | purum, ≥95.0% (AT) | 729.44元/10 G; 1496.1元/50 G; | 咨询 |
产品说明 应用 反应物或试剂用于： - Pummerer 类反应
- 二甲氧基苄基醚的化学选择性脱保护
- 介导氧化环异构化
- 苯胺类的甲氧基化
其他说明 用于脱氢和氧化反应的试剂，综述；酰胺直接转化成胺(Hofmann-型重排反应)的新型试剂，以及羧基端多肽测序的关键物质；也可用于羰基的平稳脱硫缩醛化反应 基本信息 | 线性分子式 | (CF3CO2)2IC6H5 | | 分子量 | 430.04 | | Beilstein | 764767 | | EC 号 | 220-308-0 | | MDL编号 | MFCD00009672 | | PubChem化学物质编号 | 329750783 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 等级 | purum | | 测定 | ≥95.0% (AT) | | reaction suitability | reagent type: oxidant | | mp | 121-125 ℃ (lit.)
122-125 ℃ | | SMILES string | FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1 | | InChI | 1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H | | InChI key | PEZNEXFPRSOYPL-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
|
| 910621 | Amethyst | [Bis(trifluoroacetoxy)iodo]benzene | 98%, 用于合成 | 48元/5G; 170元/25G; 538元/100G; 2146元/500G; | 咨询 |
基本信息 | 分子式 | C10H5F6IO4 | | 分子量 | 430.03 | | 熔点 | 121-125 | | MDL编码 | MFCD00009672 | | Beilstein | 764767 | | EINECS 编号 | 220-308-0 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
|
| 009038 | Fluorochem | [Bis(trifluoroacetoxy)iodo]benzene | 95% | 220元/1g; 550元/5g; 836元/25g; 1408元/100g; | 咨询 |
基本信息 | CAS Number | 2712-78-9 | | MDL Number | MFCD00009672 | | Melting Point | 122-129℃ | | Density | 1.95 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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