CAS 26386-88-9; 二甲基磷酸基叠氮化物; diphenylphosphorazidate

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货号

品牌

产品名称

规格

包装、参考价格

D807002

MACKLIN

叠氮磷酸二苯酯

97%

29元/5g; 34元/25g; 81元/100g; 342元/500g; 1570元/2.5kg; 6195元/10kg;

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储存：2~8°C
状态：无色到黄色到琥珀色液体
折射率：n20/D 1.551(lit.)

D1672

TCI

Diphenylphosphoryl Azide

>97.0%(GC)

205元/5G; 545元/25G; 3100元/250G;

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基本信息

纯度/分析方法	>97.0%(GC)
分子式/分子量	C₁₂H₁₀N₃O₃P = 275.20
外观与形状(20℃)	液体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解),加热
Reaxys-RN	2058967
PubChem物质ID	87568148
MDL编号	MFCD00001987

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 97.0 %

物性(参考值)

比重	1.28
折射率	1.55
水溶性	与水接触发生分解,不溶
溶解性(易溶于)	丙酮,二甲基甲酰胺,甲苯

安全信息

图形或危害标志
信号词	危险
危险性说明	H300 + H310 + H330 : 吞咽、皮肤接触或吸入致命。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P262 : 严防进入眼中、接触皮肤或衣服。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P284 : [在通风不足的情况下]戴呼吸防护装置。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P302 + P352 + P310 : 如皮肤沾染：用水充分清洗。立即呼叫急救中心/医生。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P405 : 存放处须加锁。

运输信息

UN编号	UN3278
类别	6.1
包装类别	II
监管条件代码(*)

130992

J&K

Diphenylphosphoryl Azide

98%

66元/5G; 238元/25G; 343元/100G;

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基本信息

分子式	C₁₂H₁₀N₃O₃P
分子量	275.20
沸点	157
闪点	112
密度	1.273
折光率(n20D)	1.5510
MDL编码	MFCD00001987
Beilstein	2058967
EINECS 编号	247-644-0
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H311 H331 H315 H319 H335
防范说明	P261 P280 P301+P310 P305+P351+P338 P311
UN号码	3278
危险分类	6.1
包装等级	II
WGK	3
TSCA	否

A12124

Alfa Aesar

Diphenylphosphonic azide

97%

317元/5g; 653元/25g; 1999元/100g;

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应用
Diphenylphosphonic azide acts as a reagent for the synthesis of peptides and phosphoramidates by reacting with amines. It is also used in the preparation of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtis rearrangement. It is involved in pseudohalogen replacement of the azido group by treatment with nucleophilic reagents, such as water, butanol, ammonia, and various amines. Further, it is used as a hydroazidation catalyst for preparation of organoazides.

备注
Store in a cool place. Incompatible with acids and oxidizing agents.

基本信息

MDL
MFCD00001987

EINECS
247-644-0

分子式
C₁₂H₁₀N₃O₃P

分子量
275.20

沸点
161-162°/0.5mm

闪点
>110°(230°F)

密度
1.275

折射率
1.5520

灵敏度
Keep Cold.

形态
Liquid

溶解性
Immiscible with water.

Beilstein
2058967

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H331-H315-H319-H335
Toxic if swallowed.Toxic in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
23/24/25-36/37/38
Toxic by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
4-9-20-23-26-27-36/37/39-45-60
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

TSCA
否

C40904

Alfa Aesar

Diphenylphosphoryl Azide

98%

1493元/25g; 3372元/100g; 17556元/500g;

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基本信息

Ref#
40904

MDL
1987

分子式
C12 H10 N3 O3 P

分子量
275.19

闪点
112

密度
1273

形态
Colorless to pale yellow liquid

安全信息

危险等级
6.1

包装组
II

178756

Sigma-Aldrich

Diphenyl phosphoryl azide

97%

263.17元/5 G; 760.33元/25 G; 2177.86元/100 G; 10344.8元/500 G; 12183.3元/5 KG;

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产品说明

应用

四苯基钴卟啉催化的烯烃氮杂环化反应。
氢氧叠氮催化有机叠氮化物粗制备

在改良Curtis重排反应中，用作合成连接氨基甲酸酯和尿素键的低聚糖合成试剂
在制备大环内酰胺和醛糖还原酶抑制剂过程中，用作活化剂。

包装

5, 25, 100, 500 g in glass bottle
5 kg in poly drum

基本信息

线性分子式	(C₆H₅O)₂P(O)N₃
分子量	275.20
Beilstein	2058967
EC 号	247-644-0
MDL编号	MFCD00001987
PubChem化学物质编号	24850766

产品性质

质量水平	200
测定	97%
形式	liquid
reaction suitability	reaction type: click chemistry
折射率	n20/D 1.551 (lit.)
bp	157 ℃/0.17 mmHg (lit.)
密度	1.277 g/mL at 25 ℃ (lit.)
储存温度	2-8℃
SMILES string	[N-]=[N+]=NP(=O)(Oc1ccccc1)Oc2ccccc2
InChI	1S/C12H10N3O3P/c13-14-15-19(16,17-11-7-3-1-4-8-11)18-12-9-5-2-6-10-12/h1-10H
InChI key	SORGEQQSQGNZFI-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H301 + H311 + H331 - H315 - H319 - H335
预防措施声明	P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
危险分类	Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 3
闪点(F)	233.6 °F - closed cup
闪点(C)	112 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

981672

Amethyst

Diphenylphosphoryl Azide

98%, 用于合成

42元/5G; 68元/25G; 176元/100G; 572元/500G;

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基本信息

分子式	C₁₂H₁₀N₃O₃P
分子量	275.20
沸点	157
闪点	112
密度	1.273
折光率(n20D)	1.5510
MDL编码	MFCD00001987
Beilstein	2058967
EINECS 编号	247-644-0
存储条件	Store at 2-8℃

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H319 H331 H335
防范说明	P280 P301+P310 P305+P351+P338
UN号码	3278
危险分类	6.1
包装等级	II
WGK	3
TSCA	否

035952

Fluorochem

Diphenylphosphoryl Azide

98%

264元/10g; 374元/25g; 1166元/100g;

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基本信息

CAS Number	26386-88-9
MDL Number	MFCD00001987
Boiling Point	157℃
Density	1.273

安全信息

图形或危害标志
危险性说明	H301: Toxic if swallowed. H310: Fatal in contact with skin. H330: Fatal if inhaled.
防范说明	P260: Do not breathe . P262: Do not get in eyes, on skin, or on clothing. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P284: Wear respiratory protection. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P350: IF ON SKIN: Gently wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310: Immediately call a POISON CENTER or doctor/physician. P320: Specific treatment is urgent (see . on this label). P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.