基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H315 H319 H335
防范说明	P261 P280 P301+P312 P302+P352 P305+P351+P338
WGK	3

基本信息

MDL
MFCD00003853

EINECS
220-069-2

分子式
(C₆H₁₁)₃P

分子量
280.42

熔点
76-78°

形态
Solid

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

应用
Tricyclohexylphosphine is used as a ligand in organometallic chemistry. As a reagent, it is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs?’catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

备注
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003853

EINECS
220-069-2

分子式
(C₆H₁₁)₃P

分子量
280.42

熔点
76-78°

灵敏度
Air Sensitive. Store under Argon. Ambient temperatures.

形态
Solid

溶解性
Soluble in most organic solvents. Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

应用
Used as an active pharmaceutical ingredient. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.

备注
Store under dry inert gas. Keep away from oxidizing agents.

基本信息

MDL
MFCD00003853

EINECS
220-069-2

分子式
(C₆H₁₁)₃P

分子量
280.42

熔点
76-78°

灵敏度
Air Sensitive. Store under Argon. Ambient temperatures.

形态
Crystalline

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

基本信息

Ref#
42161

MDL
3853

分子式
C18 H33 P

分子量
280.42

产品说明

包装

1, 5, 25, 250 g in glass bottle

应用

用于丙二腈与芳基卤化物的钯催化偶联反应的配体。大位阻膦配体，与 Pd(0)-三烯酸大环催化剂一起用于芳基溴化物和氯化物的 Suzuki 偶联反应。
该配体与镍可用作形成环戊烷化合物的关键中间体。

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

产品说明

应用

Catalyst for:

• Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
• Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
• Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
• Synthesis of (-)-Exiguolide and its analogues
• Allylation of zinc enolates

包装

100, 500 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H304 - H315 - H319 - H335 - H336 - H361d - H373 - H412
预防措施声明	P210 - P273 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 - P331
危险分类	Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2
靶器官	Central nervous system
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	51.8 °F - closed cup
闪点(C)	11 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

产品说明

应用

Catalyst for:

• Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
• Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
• Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
• Synthesis of (-)-Exiguolide and its analogues
• Allylation of zinc enolates

包装

100 mL in Sure/Seal™

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H304 - H315 - H319 - H335 - H336 - H361d - H373 - H412
预防措施声明	P210 - P273 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 - P331
危险分类	Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2
靶器官	Central nervous system
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	39.2 °F - closed cup
闪点(C)	4 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .