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CAS: 26164-26-1
分子式: C9H10O3
分子量: 166.17
熔点: 64-67℃
中文名称: 
(S)-(+)-α-甲氧基苯基乙酸
英文名称: 
(S)-(+)-α-Methoxyphenylacetic acid
O-Methyl-L-mandelic acid
(S)-(+)-à-Methoxyphenylacetic acid
O-Methyl-(S)-mandelic acid
(S)-(+)-alpha-methoxyphenylacetic acid
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S837993MACKLIN(S)-(+)-α-甲氧基苯乙酸98 %52元/1g;   186元/5g;   623元/25g;   展开
储存:室温,干燥
状态:白色固体
M0829TCI(S)-(+)-α-Methoxyphenylacetic Acid>98.0%(GC)(T)590元/1G;   1690元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H10O3 = 166.18
外观与形状(20℃)固体
Reaxys-RN2209197
PubChem物质ID87572827
MDL编号MFCD00064216

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Optical purity(LC)min. 98.0 ee%
Purity(Neutralization titration)min. 98.0 %
Melting point64.0 to 69.0 ℃

物性(参考值)

熔点66 ℃
沸点130 ℃/0.7 mmHg
比旋光度 [α]D147° (C=0.5,EtOH)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
441219J&K(S)-(+)-α-Methoxyphenylacetic acid99%, 手性衍生化试剂199元/250MG;   656元/1G;   2736元/5G;   展开

基本信息

分子式C9H10O3
分子量166.17
熔点64-66
比旋光度([α]20D)+147° to +151° (C= 0.5, Ethanol)
MDL编码MFCD00064216
Beilstein2361718
EINECS 编号247-492-5

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
L08748Alfa Aesar(S)-(+)-alpha-Methoxyphenylacetic acid99%870元/250mg;   2722元/1g;   展开

基本信息

MDL
MFCD00064216

EINECS
247-492-5

分子式
C9H10O3

分子量
166.18

熔点
63-68°

沸点
164-166°/18mm

灵敏度
Ambient temperatures.

形态
Powder

Beilstein
2361718

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C22449Alfa Aesar(S)-(+)-alpha-Methoxyphenylacetic acid99%2145元/1g;   8630元/5g;   展开

基本信息

Ref#
22449

MDL
64216

分子式
C9 H10 O3

分子量
166.18

248983Sigma-Aldrich(S)-(+)-α-Methoxyphenylacetic acid99%2075.72元/1 G;   展开

产品说明

应用

Reactant involved in the synthesis of biologically active molecules including:

  • Acyclonucleoside phosphonates structural analogs of adefovir
  • Labeled discodermolide for studying binding to tubulin
  • 10-Isocyano-4-cadinene used for antifouling activity

Reactant involved in studies of immunostimulating chromanones gonytolides A-C
Reactant involved in:
  • Hydroxylations and epoxidations
  • Hydrogenations

包装

1 g in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

基本信息

线性分子式C6H5CH(OCH3)CO2H
分子量166.17
Beilstein2361718
EC 号247-492-5
MDL编号MFCD00064216
PubChem化学物质编号24854969
NACRESNA.22

产品性质

质量水平100
测定99%
旋光性[α]17/D +150°, c = 1 in ethanol
mp64-66 ℃ (lit.)
SMILES stringCO[C@H](C(O)=O)c1ccccc1
InChI1S/C9H10O3/c1-12-8(9(10)11)7-5-3-2-4-6-7/h2-6,8H,1H3,(H,10,11)/t8-/m0/s1
InChI keyDIWVBIXQCNRCFE-QMMMGPOBSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
044963Fluorochem(S)-(+)-a-Methoxyphenylacetic acid98%1078元/1g;   1848元/5g;   5478元/25g;   13662元/100g;   展开

基本信息

CAS Number26164-26-1
MDL NumberMFCD00064216
Boiling Point164-166℃
Melting Point63-68℃
Density1.1708

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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