| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| M812967 | MACKLIN | 甲氧甲酰基亚甲基三苯基膦 | 98% | 36元/25g; 112元/100g; 535元/500g; | 展开 |
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| T1363 | TCI | Methyl (Triphenylphosphoranylidene)acetate | >98.0%(T)(HPLC) | 495元/25G; 1750元/100G; | 展开 |
基本信息 | 纯度/分析方法 | >98.0%(T)(HPLC) | | 分子式/分子量 | C21H19O2P = 334.35 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 618430 | | PubChem物质ID | 87577130 | | SDBS (AIST Spectral DB) | 29859 | | MDL编号 | MFCD00008455 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(HPLC) | min. 98.0 area% | | Purity(Ester Value) | min. 98.0 % | | Melting point | 168.0 to 172.0 ℃ |
物性(参考值) |
| 292464 | J&K | Methyl (Triphenylphosphoranylidene)acetate | 98% | 392元/25G; 1012元/100G; | 展开 |
基本信息 | 分子式 | C21H19O2P | | 分子量 | 334.35 | | 熔点 | 168-172 | | MDL编码 | MFCD00008455 | | Beilstein | 618430 | | EINECS 编号 | 220-018-4 |
安全信息 |
| A14020 | Alfa Aesar | (Methoxycarbonylmethylene)triphenylphosphorane | 98% | 1039元/25g; 3617元/100g; 18087元/500g; | 展开 |
应用
(Methoxycarbonylmethylene)triphenylphosphorane is used in olefination reactions. Further, it undergoes the Wittig reaction with aldehydes to give substituted methyl acrylates. It is used in the preparation of (triphenylphosphoranylidene)-ketene. 备注
Air sensitive. Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00008455 EINECS
220-018-4 分子式
CH3O2CCH=P(C6H5)3 分子量
334.36 熔点
165-169° 灵敏度
Air Sensitive. Store under Nitrogen. Ambient temperatures. 形态
Crystalline powder 溶解性
Soluble in chloroform. Slightly soluble in ethanol and terahydrofuran. Insoluble in water. Beilstein
618430 安全信息 危险等级
6.1 包装组
III TSCA
是 |
| C16956 | Alfa Aesar | Methyl (Triphenylphosphoranylidene)acetate | 98% | 1562元/25g; 4639元/100g; 27076元/500g; | 展开 |
基本信息 Ref#
16956 MDL
8455 分子式
C21 H19 O2 P 分子量
334.34 形态
White to cream cryst powder 安全信息 危险等级
6.1 包装组
III |
| 157929 | Sigma-Aldrich | Methyl (Triphenylphosphoranylidene)acetate | 98% | 160.47元/5 G; 400.1元/25 G; 509.12元/100 G; | 展开 |
产品说明 包装 5, 25, 100 g in poly bottle 应用 Wittig 试剂，用于醛的二碳同素化反应生成 α,β-不饱和酯。在三乙胺存在的条件下，也可用于与重氮基乙酸甲酯反应高效合成吡唑。 基本信息 | 线性分子式 | (C6H5)3P=CHCO2CH3 | | 分子量 | 334.35 | | Beilstein | 618430 | | EC 号 | 220-018-4 | | MDL编号 | MFCD00008455 | | PubChem化学物质编号 | 24849709 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 98% | | 形式 | powder | | reaction suitability | reaction type: C-C Bond Formation | | mp | 168-172 ℃ (lit.) | | SMILES string | COC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3 | | InChI | 1S/C21H19O2P/c1-23-21(22)17-24(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17H,1H3 | | InChI key | NTNUDYROPUKXNA-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 003702 | Fluorochem | (Carbomethoxymethylene)triphenylphosphorane | 98% | 220元/5g; 242元/10g; 308元/25g; 814元/100g; | 展开 |
基本信息 | CAS Number | 2605-67-6 | | MDL Number | MFCD00008455 | | Melting Point | 164-173℃ | | Density | 1.17 |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
| | 防范说明 | P264: Wash hands thoroughly after handling.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
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