CAS 25360-32-1; 羰酰二氢三(三苯基膦)钌(II); carbonyl(dihydrido)tris(triphenylphospineruthenium (ii)

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C805719

MACKLIN

羰酰二氢三(三苯基膦)钌(II)

99%

64元/250mg; 229元/1g; 872元/5g; 4246元/25g; 11463元/100g;

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储存：2~8°C
状态：白色到灰色粉末

C2251

TCI

Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)

450元/250MG; 1185元/1G;

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基本信息

分子式/分子量	C₅₅H₄₇OP₃Ru = 917.97
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	14378290
PubChem物质ID	87560473
MDL编号	MFCD00015870

技术规格

Appearance	White to Light gray powder to crystal
Elemental analysis(Carbon)	69.8 to 73.4 %
Functionality test	to pass test

物性(参考值)

熔点

163 ℃

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 : 吞咽有害。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P264 : 作业后彻底清洗皮肤。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。

44-0100

Strem

Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II)

99%

795元/250mg; 2385元/1g;

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Technical Notes:

1.Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.

2.Catalytic c-C bond formation

3.Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.

4.Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.

5.Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.

6.Precatalyst for hydrogen production by means of alcohol dehydrogenation.

References: 1.Org. L ett, 2009, 11, 1951 . 2.Org. Lett., 2009, 1 1, 5426. 3.Chem. Eur. J., 2009, 15, 7530. 4.J. Am. Chem. Soc., 2009, 131, 7238. 5.Org. L ett., 2009, 11, 855. 6.J. Am. Chem. Soc., 2007, 129, 6098. 7.J. Am. Chem. Soc., 2008, 130, 14120. 8.Dalton Trans., 2009, 716. 9.Adv. Synth. Catal., 2008, 350, 1975. 10.Synthesis, 2009, 9, 157 8. 11.Angew. Chem. Int. Ed., 2011, 50, 9593.

040524

Alfa Aesar

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

99%

2536元/0.5g; 8640元/2g; 38995元/10g;

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应用
Carbonyldihydridotris(triphenylphosphine)ruthenium(II) is used as Catalyst for conversion of 1,4-alkynediols into pyrroles, Catalyst for oxidation of primary alcohols to methyl esters, Catalyst for rearrangement of oximes to amides, Catalyst for C-C coupling via directed C-H activation, Catalyst for enyne cyclization.

备注
Moisture & Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00015870

分子式
C₅₅H₄₇OP₃Ru

分子量
917.97

熔点
161-163°

灵敏度
Moisture Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.

Precautionary Statements
P261-P280h-P304+P340-P301+P312a-P321-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/clothing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Specific treatment (see label).Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22
Harmful by inhalation, in contact with skin and if swallowed.

安全等级
9-36/37-60
Keep container in a well-ventilated place.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

335002

Sigma-Aldrich

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

1127.6元/1 G;

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产品说明

应用

用于将 1,4-烷二醇转化为吡咯的催化剂
用于将伯醇氧化成甲酯的催化剂
用于将肟重排成酰胺的催化剂
通过定向 C-H 活化进行 C-C 偶联的催化剂
环戊烷环化的催化剂

包装

1 g in glass bottle

基本信息

线性分子式	[(C₆H₅)₃P]₃Ru(CO)H₂
分子量	919.79
PubChem化学物质编号	24860277
NACRES	NA.22

产品性质

质量水平	100
reaction suitability	core: ruthenium reagent type: catalyst reaction type: C-H Activation
mp	161-163 ℃ (lit.)
SMILES string	[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.CO.Ru.2H/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h31-15H;;;;
InChI key	MLIYPCQSOXNTLJ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332
预防措施声明	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves