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CAS: 25260-60-0
分子式: C8H12O4
分子量: 172.18
沸点: 120℃(18
中文名称: 
顺-1,4-二醋酸基-2-丁烯
英文名称: 
cis-1,4-diacetoxy-2-butene
cis-2-Butene-1,4-diol diacetate
推荐供应商
货号品牌产品名称规格包装、参考价格
D836360MACKLINcis-1,4-二乙酰氧基-2-丁烯98%372元/5g;   680元/25g;   2699元/100g;   咨询
储存:2-8°C
状态:无色到浅黄色到黄色液体
D1358TCIcis-1,4-Diacetoxy-2-butene>95.0%(GC)630元/25ML;   4070元/500ML;   咨询

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C8H12O4 = 172.18
外观与形状(20℃)液体
Reaxys-RN1724379
PubChem物质ID87567872
SDBS (AIST Spectral DB)659
MDL编号MFCD00059339

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点110 ℃/13 mmHg
比重1.09
L13024Alfa Aesarcis-1,4-Diacetoxy-2-butene96%496元/10g;   1818元/50g;   咨询

应用
cis-1,4-Diacetoxy-2-butene is used as an organic chemical synthesis intermediate.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00059339

EINECS
000-000-0

分子式
C8H12O4

分子量
172.18

沸点
120-121°/18mm

闪点
>110°(230°F)

密度
1.090

折射率
1.4416

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Not miscible in water.

Beilstein
1724379

安全信息

TSCA
否

C43126Alfa Aesarcis-1,4-Diacetoxy-2-butene95%2024元/25ml;   咨询

基本信息

Ref#
43126

MDL
59339

分子式
C8 H12 O4

分子量
172.18

闪点
>113

密度
1.08

468037Sigma-Aldrichcis-1,4-Diacetoxy-2-butene95%904.44元/25 ML;   咨询

产品说明

一般描述

cis-1,4-Diacetoxy-2-butene is an ester. Ruthenium olefin metathesis catalysts having cyclic (alkyl)(amino)carbenes effectively catalyzes the cross-metathesis of cis-1,4-diacetoxy-2-butene with allylbenzene. cis-1,4-Diacetoxy-2-butene on pyrolysis affords 1-acetoxy-1,3-butadiene, a diacetate and an isomeric 1,2-diacetoxy-3-butene. Mechanism of pyrolysis has been investigated.

应用

cis-1,4-Diacetoxy-2-butene may be used in the preparation of hindered Diels-Alder adducts. It may be used for the synthesis of 1,2,3,4-tetrahydro-2-vinylquinoxalines, via Palladium-catalyzed tandem allylation of 1,2-phenylenediamines.

包装

25 mL in glass bottle

基本信息

线性分子式CH3CO2CH2CH=CHCH2O2CCH3
分子量172.18
MDL编号MFCD00059339
PubChem化学物质编号24870459
NACRESNA.22

产品性质

质量水平100
测定95%
折射率n20/D 1.443 (lit.)
bp120-121 ℃/18 mmHg (lit.)
密度1.08 g/mL at 25 ℃ (lit.)
SMILES string[H]\C(COC(C)=O)=C(/[H])COC(C)=O
InChI1S/C8H12O4/c1-7(9)11-5-3-4-6-12-8(2)10/h3-4H,5-6H2,1-2H3/b4-3-
InChI keyVZUAUHWZIKOMFC-ARJAWSKDSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315
危险分类Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
238796Fluorochem(Z)-But-2-ene-1,4-diyl diacetate95%220元/1g;   396元/5g;   1078元/25ml;   5918元/500ml;   咨询

基本信息

CAS Number25260-60-0
MDL NumberMFCD00059339

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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