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CAS: 2524-64-3
分子式: C12H10ClO3P
分子量: 268.63
沸点: 314-316℃
中文名称: 
氯磷酸二苯酯
磷酰氯二苯酯
二苯基氯磷酸酯
英文名称: 
Phosphorochloridic acid,diphenyl ester
Diphenyl chlorophosphonate
Diphenyl phosphorochloridate
Diphenyl phosphoryl chloride
Chlorodiphenyl Phosphate
Phosphorochloridic Acid Diphenyl Ester
diphenylphosphoryl chloride
Phosphorochloridic acid, diphenyl ester
diphenyl chlorophosphate
推荐供应商
货号品牌产品名称规格包装、参考价格
D807313MACKLIN氯代磷酸二苯酯97%30元/25g;   41元/100g;   134元/500g;   483元/2.5kg;   咨询
储存:室温,干燥
状态:无色液体
折射率:n20/D 1.55(lit.)
D1059TCIDiphenyl Chlorophosphate>95.0%(GC)195元/25G;   430元/100G;   1580元/500G;   咨询

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C12H10ClO3P = 268.63
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN654130
PubChem物质ID87567629
SDBS (AIST Spectral DB)7038
MDL编号MFCD00003030

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点316 ℃/272 mmHg
比重1.30
折射率1.55

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3265
类别8
包装类别 III
监管条件代码(*)
124811J&KDiphenyl phosphoryl chloride99%87元/25G;   231元/100G;   咨询

基本信息

分子式C12H10ClO3P
分子量268.64
沸点314-316
闪点>113
密度1.296
折光率(n20D)1.5500
MDL编码MFCD00003030
Beilstein654130
EINECS 编号219-759-6

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK2
TSCA
A13546Alfa AesarDiphenyl Phosphorochloridate97%402元/50g;   1426元/250g;   4372元/1000g;   咨询

应用
Diphenyl phosphorochloridate is used to prepare cyclohexyl-amidophosphoric acid diphenyl ester by reacting with cyclohexylamine. It is also used in the synthesis of alfa-substituted beta-lactams, anhydrides, esters and thioesters. It is also employed in the conversion of aldoximes to nitriles. Further, it is used in the preparation and reaction of enol phosphates, guanosine-adenosine-5',5'-triphosphate, guanosine-cytidine-5',5'-triphosphate, guanosine-uridine-5',5'-triphosphate, diguanosine-5',5'-diphosphate and diguanosine-5',5'-triphosphate. In addition to this, it serves as a phosphorylating agent for the preparation of 2-deoxy-D-galactose-3 and -6 phosphoric acids.

备注
Moisture sensitive. Incompatible with strong bases and strong oxidizing agents.

基本信息

MDL
MFCD00003030

EINECS
219-759-6

分子式
C12H10ClO3P

分子量
268.64

沸点
145-147°/1mm

闪点
113°(235°F)

密度
1.296

折射率
1.5500

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Immiscible with water.

Beilstein
654130

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C11724Alfa AesarDiphenyl Chlorophosphate98%887元/25ml;   1256元/100ml;   4641元/500ml;   咨询

基本信息

Ref#
11724

MDL
3030

分子式
C12 H10 Cl O3 P

分子量
268.63

闪点
>112

密度
1.29

安全信息

危险等级
8

包装组
II

344249Sigma-AldrichDiphenyl phosphoryl chloride96%808.9元/100 G;   3997.1元/500 G;   咨询

产品说明

一般描述

Diphenyl phosphoryl chloride is a diaryl phosphoryl derivative. It is formed during the preparation of monophenyl phosphoryl chloride via reaction of phenol and phosphorus oxychloride.

应用

Diphenyl phosphoryl chloride may be used:

  • in the preparation of guanosine-adenosine-5′,5′-triphosphate, guanosine-cytidine-5′,5′-triphosphate, guanosine-uridine-5′,5′-triphosphate, diguanosine-5′,5′-diphosphate and diguanosine-5′,5′-triphosphate
  • as phosphorylating agent for the synthesis of 2-deoxy-D-galactose-3 and -6 phosphoric acids
  • in the synthesis of diaryl phosphoryl derivatives of alkylene dithiophosphates

包装

100, 500 g in glass bottle

基本信息

线性分子式(C6H5O)2POCl
分子量268.63
Beilstein654130
EC 号219-759-6
MDL编号MFCD00003030
PubChem化学物质编号24861235
NACRESNA.22

产品性质

质量水平100
蒸汽压10 mmHg ( 190 ℃)
测定96%
折射率n20/D 1.55 (lit.)
bp314-316 ℃/272 mmHg (lit.)
密度1.296 g/mL at 25 ℃ (lit.)
SMILES stringClP(=O)(Oc1ccccc1)Oc2ccccc2
InChI1S/C12H10ClO3P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H
InChI keyBHIIGRBMZRSDRI-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314
预防措施声明P270 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)> 113 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
D206555Sigma-AldrichDiphenyl phosphoryl chloride99%353.77元/25 G;   1092.73元/100 G;   咨询

产品说明

应用

保护性丝氨酸和吡喃糖的磷酸化试剂。

包装

25, 100 g in glass bottle

基本信息

线性分子式(C6H5O)2POCl
分子量268.63
Beilstein654130
EC 号219-759-6
MDL编号MFCD00003030
PubChem化学物质编号24893614
NACRESNA.22

产品性质

质量水平200
蒸汽压10 mmHg ( 190 ℃)
测定99%
折射率n20/D 1.55 (lit.)
bp314-316 ℃/272 mmHg (lit.)
密度1.296 g/mL at 25 ℃ (lit.)
SMILES stringClP(=O)(Oc1ccccc1)Oc2ccccc2
InChI1S/C12H10ClO3P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H
InChI keyBHIIGRBMZRSDRI-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314
预防措施声明P270 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)> 113 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
226729AmethystDiphenyl phosphoryl chloride97%, 用于合成41元/25G;   103元/100G;   415元/500G;   咨询

基本信息

分子式C12H10ClO3P
分子量268.64
沸点314-316
闪点>113
密度1.296
折光率(n20D)1.548 - 1.552
MDL编码MFCD00003030
Beilstein654130
EINECS 编号219-759-6

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3265
危险分类8
包装等级II
WGK2
TSCA
212482FluorochemDiphenyl Chlorophosphate99%220元/1g;   286元/25g;   770元/100g;   2200元/500g;   4180元/1kg;   咨询

基本信息

CAS Number2524-64-3
MDL NumberMFCD00003030
Boiling Point314 - 316 ℃ at 363 hPa - lit.
Density1.296

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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