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CAS: 252288-04-3
分子式: C24H22NO2P
分子量: 387.4
中文名称: 
(S)-(+)-(3,5-二氧-4-磷环烷[2,1-a;3,4-a']4-二萘基)二乙基胺
英文名称: 
(S)-(+)-(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)diethylamine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S853915MACKLIN(11bS)​-N,​N-​二乙基-联萘并[2,​1-​d:1',​2'-​f]​[1,​3,​2]二氧膦杂-​4-​胺98%,99% e.e.151元/250mg;   536元/1g;   展开
储存:室温,干燥
状态:白色到灰白色粉末或晶体
15-1231Strem(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)diethylaminemin. 97%778元/250mg;   2336元/1g;   展开

Technical Notes:

1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.

2. Ligand used in the enantioselective, iridium- catalyzed allylic substitution of allyl acetates containing only a single substituent

3.Ligan use in the rhodium-catalvzed. amide

4 Ligand usedithaesrhodericataluaate additiodrecaed' boronieatciastdaingatinitronathtalenes

5: Ligand used in the rhoaium-cataiyaea asymmetricaintramoieculari, aditionitronaphtn

References:

1.J. Am. Chem. Soc., 2000, 122, 11 539.

2.Adv. Synth. ( atal., 2003, 345, 308.

3.Adv. Synth. Catal., 2002, 344, 1003.

4.Chem. Comm, 1999, 741.

5.Eur. J. Inorg. Chem., 2002, 2569.

6.J. Am. Chem. Soc., 2008, 1 3o, 3734.

7.Ad. Synth. Catal, 2012, 354, 2433.

8.J. Org. Chem., 2013, 78, 2736.

Y24216Alfa Aesar(11bS)-N,N-Diethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]442元/100mg;   718元/250mg;   2449元/1g;   展开

基本信息

分子量
387.41

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