CAS 2417-72-3; 4-溴甲基苯甲酸甲酯; Methyl 4-bromomethylbenzoate

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货号

品牌

产品名称

规格

包装、参考价格

M814358

MACKLIN

4-(溴甲基)苯甲酸甲酯

98.0%

31元/5g; 148元/25g; 579元/100g; 2881元/500g;

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储存：室温,密封
状态：白色到黄色粉末或晶体

B2053

TCI

Methyl 4-(Bromomethyl)benzoate

>98.0%(GC)

490元/10G; 980元/25G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₉H₉BrO₂ = 229.07
外观与形状(20℃)	固体
Reaxys-RN	1867272
PubChem物质ID	87564927
MDL编号	MFCD00032453

技术规格

Appearance	White to Almost white powder to crystal
Purity(GC)	min. 98.0 %
Melting point	54.0 to 57.0 ℃

物性(参考值)

熔点

56 ℃

安全信息

图形或危害标志
信号词	危险
危险性说明	H314 : 造成严重皮肤灼伤和眼损伤。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P260 : 不要吸入粉尘或烟雾。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3261
类别	8
包装类别	III
监管条件代码(*)

183478

J&K

Methyl 4-(Bromomethyl)benzoate

98%

174元/5G; 542元/25G;

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基本信息

分子式	C₉H₉BrO₂
分子量	229.07
熔点	57-58
沸点	130-135
密度	1.470
MDL编码	MFCD00032453
Beilstein	1867272

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H314 H334
防范说明	P261 P280 P301+P310 P305+P351+P338 P310
UN号码	3261
危险分类	8
包装等级	III
WGK	3
TSCA	否

A10557

Alfa Aesar

Methyl 4-(Bromomethyl)benzoate

98%

846元/5g; 2653元/25g; 8982元/100g;

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应用
Methyl 4-(bromomethyl)benzoate is used in the preparation of potential anti-HIV agents. It i s also used as a catalyst for rearrangement of benzylthiothiazoline derivatives in the preparation aldose reductase inhibitors.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air sensitive. Handle and store under inert gas. Keep away from strong oxidizing agents, strong bases. Stable under recommended storage conditions.

基本信息

MDL
MFCD00032453

EINECS
000-000-0

分子式
C₉H₉BrO₂

分子量
229.07

熔点
53-58°

沸点
130-135°/2mm

灵敏度
Ambient temperatures.

形态
Powder/chunks

溶解性
Lowly soluble in water, highly soluble in ethanol and ether, not soluble in halogenated organic solvents

Beilstein
1867272

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

C30610

Alfa Aesar

Methyl 4-(Bromomethyl)benzoate

98%

676元/5g; 1984元/25g; 7121元/100g;

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基本信息

Ref#
30610

MDL
32453

分子式
C9 H9 Br O2

分子量
229.07

安全信息

危险等级
8

包装组
II

348155

Sigma-Aldrich

Methyl 4-(Bromomethyl)benzoate

98%

429.23元/5 G; 1116.08元/25 G;

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产品说明

一般描述

4-(溴甲基)苯甲酸甲酯是一种酯，是一种催泪物质和重要的药物中间体。酯基在4-(溴甲基)苯甲酸甲酯中略微扭曲出中心芳环的平面。

应用

4-(溴甲基)苯甲酸甲酯可用于合成9-O-(4-羧基苄基)小檗碱(CBB)。

包装

5, 25 g in glass bottle

基本信息

线性分子式	BrCH₂C₆H₄CO₂CH₃
分子量	229.07
MDL编号	MFCD00032453
PubChem化学物质编号	24861555

产品性质

质量水平	100
测定	98%
bp	130-135 ℃/2 mmHg (lit.)
mp	57-58 ℃ (lit.)
SMILES string	COC(=O)c1ccc(CBr)cc1
InChI	1S/C9H9BrO2/c1-12-9(11)8-4-2-7(6-10)3-5-8/h2-5H,6H2,1H3
InChI key	NLWBJPPMPLPZIE-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H301 - H314 - H334
预防措施声明	P260 - P280 - P301 + P310 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
危险分类	Acute Tox. 3 Oral - Resp. Sens. 1 - Skin Corr. 1B
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

036150

Fluorochem

Methyl 4-bromomethylbenzoate

98%

264元/5g; 616元/25g; 1650元/100g; 6600元/500g;

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基本信息

CAS Number	2417-72-3
MDL Number	MFCD00032453

安全信息

图形或危害标志
危险性说明	H301: Toxic if swallowed. H314: Causes severe skin burns and eye damage. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
防范说明	P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear . P285: In case of inadequate ventilation wear respiratory protection. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P304 + P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P330: Rinse mouth. P342 + P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.