CAS 240417-00-9; 2′-(diphenylphosphino)-n,n′-dimethyl-(1,1′-biphenyl)-2-amine; phdave-phos

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货号

品牌

产品名称

规格

包装、参考价格

D807808

MACKLIN

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯

97%

38元/1g; 138元/5g;

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储存：2~8℃,干燥,密封
状态：白色到黄色固体

D4402

TCI

2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl

>98.0%(GC)(T)

980元/1G;

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基本信息

纯度/分析方法	>98.0%(GC)(T)
分子式/分子量	C₂₆H₂₄NP = 381.46
外观与形状(20℃)	固体
Reaxys-RN	9717228
MDL编号	MFCD03094578

技术规格

Appearance	White to Almost white powder to crystal
Purity(GC)	min. 98.0 %
Purity(Nonaqueous Titration)	min. 98.0 %
Melting point	124.0 to 128.0 ℃

物性(参考值)

熔点

127 ℃

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

15-1745

Strem

2-Diphenylphosphino-2'-(N,N-dimethylamino))-1,1'-biphenyl

98%

480元/500mg; 1425元/2g; 5700元/10g;

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Technical Notes:

1.Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of arylbromides.

2.Ligand used for the Cu-catalyzed phos phorylation of alcohols .

3.Ligand for Pd-catalyzed C-H benzylation.

4. Ligand for palladium-catalyzed 4 + 2 benzannulation reaction.

References:

1.Org. L ett., 2005, 7, 3271.

2.Org. L ett, 2009, 1 1, 4160.

3.Org. L ett., 2013, 15, 2562.

4.Chem Sci 2011.2.27.

695882

Sigma-Aldrich

PhDave-Phos

97%

1086.29元/1 G;

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产品说明

包装

1, 5 g in glass bottle

法律信息

用法以美国专利 6307087 和 6395916 为准。

基本信息

经验(实验)分子式	C₂₆H₂₄NP
分子量	381.45
MDL编号	MFCD03094578
PubChem化学物质编号	329761783
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	reaction type: Cross Couplings reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction reagent type: ligand reaction type: C-C Bond Formation
mp	122-126 ℃
官能团	phosphine
SMILES string	CN(C)c1ccccc1-c2ccccc2P(c3ccccc3)c4ccccc4
InChI	1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3
InChI key	JGFXUYLYPITYGR-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

216440

Fluorochem

2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl

95%

220元/250mg; 418元/1g; 1364元/5g; 2156元/10g;

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基本信息

CAS Number	240417-00-9
MDL Number	MFCD03094578
Melting Point	126-128℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .