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CAS: 2378771-65-2
中文名称: 
二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(Ⅱ)
英文名称: 
dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(ii) [nh2me2][{rucl((R)-h8-binap)}2(mu-cl)3]
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货号品牌产品名称规格包装、参考价格
44-0516StremDimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]1245元/50mg;   4980元/250mg;   咨询

Technical Notes :

1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturate carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)

2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.

References:

1. J. Org. Chem.. 1996. 61. 5510

2. Topics Organometal. Chem. 2004, 6. 63 (review).

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