CAS 23364-44-5; (1S,2R)-(-)-2-氨基-1,2-二苯基乙醇; (1S,2R)-2-Amino-1,2-diphenyl-ethanol

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货号

品牌

产品名称

规格

包装、参考价格

S801474

MACKLIN

(1S,2R)-2-氨基-1,2-二苯基乙醇

99%

28元/1g; 46元/5g; 203元/25g; 799元/100g; 2950元/500g;

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储存：2~8°C
状态：白色到灰白色粉末或晶体
折射率：7 ° (C=0.6, EtOH)

A1231

TCI

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

>99.0%(GC)(T)

100元/1G; 390元/5G;

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基本信息

纯度/分析方法	>99.0%(GC)(T)
分子式/分子量	C₁₄H₁₅NO = 213.28
外观与形状(20℃)	固体
Reaxys-RN	1212828
PubChem物质ID	87562701
SDBS (AIST Spectral DB)	19151
MDL编号	MFCD00074959

技术规格

Appearance	White to Almost white powder to crystal
Purity(GC)	min. 99.0 %
Purity(Nonaqueous Titration)	min. 99.0 %
Melting point	143.0 to 146.0 ℃
Specific rotation [a]20/D	+6.0 to +8.0 deg(C=0.6, EtOH)
Solubility in Methanol	very faint turbidity

物性(参考值)

熔点	144 ℃
比旋光度 [α]D	7° (C=0.6,EtOH)

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

229521

J&K

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

99%

173元/1G; 558元/5G; 2485元/25G;

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基本信息

分子式	C₁₄H₁₅NO
分子量	213.28
熔点	142-144
MDL编码	MFCD00074959
Beilstein	1212828

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

123338

J&K

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

98%

170元/1G; 544元/5G; 1011元/10G;

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基本信息

分子式	C₁₄H₁₅NO
分子量	213.28
熔点	142-144
MDL编码	MFCD00074959
Beilstein	1212828

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

07-0041

Strem

(1S,2R)-2-Amino-1,2-diphenylethanol

min. 98%

1390元/5g; 5970元/25g;

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Technical Notes:

1.L igand used to make chiral oxaborolidines for the enantios elective alkynylation of aldehydes

2.L igand used in organoindium reagents for asymmetric B arbier-type allylations

3.L igand used in organoindium reagents for asymmetric B arbier-type propargylations

References :

1.J. Am. Chem. Soc., 1994, 116, 3151. 2.J. Org. Chem.. 2010, 75, 642.

3.J. Org. Chem. 2012, 77, 889.

H27834

Alfa Aesar

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

98%

870元/1g; 3285元/5g;

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基本信息

MDL
MFCD00074959

分子式
C₁₄H₁₅NO

分子量
213.28

熔点
141-143°

形态
Crystalline powder

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

331880

Sigma-Aldrich

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

99%

424.02元/1 G; 1912.59元/5 G;

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产品说明

应用

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:

To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.

包装

1, 5 g in glass bottle

基本信息

线性分子式	C₆H₅CH(NH₂)CH(C₆H₅)OH
分子量	213.28
Beilstein	1212828
MDL编号	MFCD00074959
PubChem化学物质编号	24860005
NACRES	NA.22

产品性质

质量水平	100
测定	99%
旋光性	[α]25/D +7.0°, c = 0.6 in ethanol
mp	142-144 ℃ (lit.)
SMILES string	N[C@@H]([C@@H](O)c1ccccc1)c2ccccc2
InChI	1S/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14+/m1/s1
InChI key	GEJJWYZZKKKSEV-KGLIPLIRSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

048051

Fluorochem

(1S,2R)-2-Amino-1,2-diphenyl-ethanol

98%

330元/1g; 572元/5g; 924元/10g; 1650元/25g;

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基本信息

CAS Number	23364-44-5
MDL Number	MFCD00074959
Melting Point	144℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .