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CAS: 23357-52-0
分子式: C10H13N
分子量: 147.22
沸点: 118-120°C 7,6mm
中文名称: 
(S)-(+)-1,2,3,4-四氢-1-萘胺
(S)-(+)-1-氨基-1,2,3,4-四羟化萘
英文名称: 
(S)-(+)-1,2,3,4-tetrahydro-1-naphthylamine
(S)-(+)-1-amino-1,2,3,4-tetrahydronaphthalene
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S799248MACKLIN(|S|)-(+)-1,2,3,4-四氢-1-萘胺97%98元/5g;   344元/25g;   展开
储存:室温, 密封
状态:无色到棕色液体
S819671MACKLIN(|S|)-(+)-1,2,3,4-四氢-1-萘胺>99%, ee >98%44元/1g;   132元/5g;   535元/25g;   展开
储存:室温,密封
状态:无色到棕色液体
折射率:1.565
T2878TCI(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine>98.0%(GC)(T)480元/5G;   1880元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C10H13N = 147.22
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN2360279
PubChem物质ID160871161
MDL编号MFCD00671630

技术规格

AppearanceColorless to Red to Green clear liquid
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Specific rotation [a]20/D+26.0 to +30.0 deg(C=2, MeOH)

物性(参考值)

沸点77 ℃/0.6 mmHg
比重1.04
比旋光度 [α]D28° (C=2,MeOH)
折射率1.56

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
553081J&K(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine98%, ee: 98%138元/1G;   416元/5G;   1662元/25G;   展开

基本信息

分子式C10H13N
分子量147.22
沸点250
密度1.010
折光率(n20D)1.5650
MDL编码MFCD00671630
Beilstein2360279

安全信息

图形或危害标志
提示语Danger
危险说明H302
H314
H412
防范说明P280
P305+P351+P338
P310
UN号码2735
危险分类8
包装等级III
WGK3
TSCA
L17022Alfa Aesar(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamineChiPros庐 99+%, ee 99%777元/1g;   1984元/5g;   7039元/25g;   展开

应用
(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine is used as a chiral amine derivative used in studies of real-time chiral discrimination of enantiomers as well as in studies of kinetic resolution of chiral amines with ω-transaminase using an enzyme-membrane reactor.

备注
Air Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00671630

EINECS
000-000-0

分子式
C10H13N

分子量
147.22

沸点
118-120°/8mm

闪点
>110°(230°F)

密度
1.035

折射率
1.5645

灵敏度
Air Sensitive. Ambient temperatures.

溶解性
Soluble in water.

Beilstein
2360279

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

668796Sigma-Aldrich(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine97%466.27元/5 G;   1891.47元/25 G;   展开

产品说明

应用

(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine is a chiral amine that can be used:

  • To prepare a 2-pyridylmethylene-(S)-(+)-1,2,3,4-tetrahydro-1-naphthylamine containing pentanuclear trigonal bipyramidal [Co3Fe2] complex, which exhibits electron-transfer-coupled spin transition (ETCST) properties.
  • To prepare imine-substituted thiophene Schiff base compounds.
  • To derivatize macrocyclic diarylheptanoid compounds of biological importance.

包装

5, 25 g in glass bottle

法律信息

Tetralin is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式(C10H11)NH2
分子量147.22
Beilstein2360279
MDL编号MFCD00671630
PubChem化学物质编号24885002
NACRESNA.22

产品性质

质量水平100
测定97%
折射率n20/D 1.565
bp250 ℃
密度1.010 g/mL at 25 ℃
SMILES stringN[C@H]1CCCc2ccccc12
InChI1S/C10H13N/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-2,4,6,10H,3,5,7,11H2/t10-/m0/s1
InChI keyJRZGPXSSNPTNMA-JTQLQIEISA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314 - H412
预防措施声明P273 - P280 - P301 + P312 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Skin Corr. 1C
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
048221Fluorochem(S)-1-Amino-1,2,3,4-tetrahydro-naphthalene97%220元/1g;   506元/5g;   770元/10g;   1584元/25g;   展开

基本信息

CAS Number23357-52-0
MDL NumberMFCD00671630
Density1.01

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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