CAS 23294-41-9; (+)-bis[(R)-1-phenylethyl]amine hydro-chloride

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D853276

MACKLIN

(+)-双[(R)-1-苯乙基]胺

≥97%

46元/250mg; 121元/1g; 433元/5g;

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储存：室温,干燥
状态：无色液体

H27424

Alfa Aesar

(+)-Bis[(R)-1-phenylethyl]amine

ChiPros庐, 99%, ee 98+%

682元/1g; 2021元/5g; 8424元/25g;

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应用
(+)-Bis[(R)-1-phenylethyl]amine play a very extensive role of making chirally optically active drugs and compounds. Also as intermediates.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD00243088

分子式
C₁₆H₁₉N

分子量
225.34

沸点
98°/0.3mm

灵敏度
Air Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

452823

Sigma-Aldrich

(+)-Bis[(R)-1-phenylethyl]amine

99%

452.78元/1 G; 3691.16元/10 G;

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产品说明

应用

(+)-双[(R)-1-苯基乙基]胺可用于：

β-氨基酸的合成。
制备具有手性C(19)-C(26)和C(27)-C(32)部分的scytophycin C。
在前手性酮的去质子化中诱导对映选择性。
作为通过曼尼希缩合反应合成手性酚盐配体的原料。
合成手性亚磷酰胺配体。
制备手性环状异亚胺盐，其可进一步用于通过Diels-Alder反应合成手性内酯。

包装

1, 10 g in glass bottle

基本信息

线性分子式	[C₆H₅CH(CH₃)]₂NH
分子量	225.33
Beilstein	3590931
MDL编号	MFCD00243088
PubChem化学物质编号	24868728
NACRES	NA.22

产品性质

质量水平	100
测定	99%
旋光性	[α]20/D +199.0°, neat
光学纯度	ee: ≥99% (GLC)
折射率	n20/D 1.5523 (lit.)
bp	86 ℃/0.05 mmHg (lit.)
密度	0.985 g/mL at 25 ℃ (lit.)
SMILES string	C[C@@H](N[C@H](C)c1ccccc1)c2ccccc2
InChI	1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m1/s1
InChI key	NXLACVVNHYIYJN-ZIAGYGMSSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	12 - Non Combustible Liquids
WGK	WGK 3
闪点(F)	235.4 °F - closed cup
闪点(C)	> 113 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter

387029

Fluorochem

(+)-Bis[(R)-1-phenylethyl]amine

97%

1496元/1g; 4532元/5g; 13596元/25g;

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基本信息

CAS Number	23294-41-9
MDL Number	MFCD00243088

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.