CAS 2325-27-1; 四苯基氨化膦; tetraphenylphosphine imide

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货号

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产品名称

规格

包装、参考价格

详情

L00496

Alfa Aesar

Tetraphenylphosphine imide

97%

587元/1g; 2635元/5g;

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应用
Has been used as a protected form of aniline for the preparation of monoalkylanilines by alkylation and hydrolysis and as an intermediate for the preparation of isocyanates and isothiocyanates.

备注
Moisture sensitive. Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

基本信息

MDL
MFCD00003044

EINECS
219-039-1

分子式
C₂₄H₂₀NP

分子量
353.40

熔点
128-132°

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystals

溶解性
Insoluble in water. Soluble in chloroform 25 mg/mL.

Beilstein
753032

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

324876

Sigma-Aldrich

N-(Triphenylphosphoranylidene)aniline

97%

1899.65元/5 G;

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产品说明

一般描述

N-(Triphenylphosphoranylidene)aniline was reported as a new electrolyte additive for high performance lithium cobalt oxide (LiCoO₂) electrodes during high voltage operations in lithium ion batteries.

应用

The Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic Method

Intermediate for the preparation of isocyanates and isothiocyanates.

包装

5 g in glass bottle

基本信息

线性分子式	(C₆H₅)₃P=NC₆H₅
分子量	353.40
EC 号	219-039-1
MDL编号	MFCD00003044
PubChem化学物质编号	24859473
NACRES	NA.22

产品性质

测定	97%
杂质	<0.5% denatured ethanol
溶解性	chloroform: soluble 25 mg/mL, clear to slightly hazy (colorless to brown)
SMILES string	c1ccc(cc1)N=P(c2ccccc2)(c3ccccc3)c4ccccc4
InChI	1S/C24H20NP/c1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H
InChI key	PTLOPIHJOPWUNN-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves