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CAS: 2325-10-2
分子式: C14H14O2
分子量: 214.26
熔点: 147-150℃
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S858391MACKLIN(S,S)-(-)-氢化苯偶姻99%133元/1g;   446元/5g;   2070元/25g;   展开
储存:室温,干燥
状态:白色到灰白色固体
H0824TCI(S,S)-(-)-Hydrobenzoin>99.0%(GC)150元/100MG;   725元/5G;   2705元/25G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C14H14O2 = 214.26
外观与形状(20℃)固体
Reaxys-RN2330888
PubChem物质ID87571182
Merck Index (14)4777
MDL编号MFCD00064255

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 99.0 %
Optical purity(LC)min. 98.0 ee%
Melting point146.0 to 150.0 ℃

物性(参考值)

熔点148 ℃
比旋光度 [α]D-95° (C=1,CHCl3)
547938J&K(S,S)-(-)-Hydrobenzoin98%76元/100MG;   133元/500MG;   656元/5G;   展开

基本信息

分子式C14H14O2
分子量214.26
熔点148-150
比旋光度([α]20D) -94° to -92°(C=2.5, EtOH)
MDL编码MFCD00064255
Beilstein2330888
Merck14,4777

安全信息

防范说明P260
P262
WGK3
TSCA
L14082Alfa Aesar(S,S)-(-)-Hydrobenzoin98+%546元/100mg;   3092元/500mg;   展开

基本信息

MDL
MFCD00064255

分子式
C14H14O2

分子量
214.27

熔点
148-150°

形态
Crystals

Beilstein
2330888

Merck
14,4777

安全信息

TSCA

256269Sigma-Aldrich(S,S)-(-)-Hydrobenzoin99%, optical purity ee: 99% (GLC)840.93元/5 G;   2829.78元/25 G;   展开

产品说明

一般描述

手性试剂。

应用

C2 对称手性二醇,具有多种用途如手性助剂、结构单元 和手性配体。
(S,S)-(-)-氢化安息香还可用于制备(1S,2S,1′S)-及(1S,2S,1′R)-2-(环己-2′-烯氧基)-1,2-二苯乙醇,而这是制备对映纯环己糖醇的一种中间体。 (S,S)-(-)-氢化安息香/Ca络合物可用于催化苯乙酮和新戊醛的直接不对称羟醛反应以形成(R)-3-羟基-4,4-二甲基-1-苯基戊基-1-酮。

包装

5, 25 g in glass bottle

其他说明

斯克里普斯代谢组学和质谱技术中心独立生成的串联质谱数据可以 PDF 形式 ( 256269.pdf ) 查看或下载。该中心的 METLIN 代谢物数据库中有测试代谢物。要了解更多信息,请访问 sigma.com/metlin。

基本信息

线性分子式C6H5CH(OH)CH(OH)C6H5
分子量214.26
Beilstein2330888
MDL编号MFCD00064255
PubChem化学物质编号24855513
NACRESNA.22

产品性质

测定99%
旋光性[α]24/D −94°, c = 2.5 in ethanol
光学纯度ee: 99% (GLC)
mp148-150 ℃ (lit.)
SMILES stringO[C@H]([C@@H](O)c1ccccc1)c2ccccc2
InChI1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14-/m0/s1
InChI keyIHPDTPWNFBQHEB-KBPBESRZSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
454959Fluorochem(1S,2S)-1,2-Diphenylethane-1,2-diol95%418元/1g;   展开

基本信息

CAS Number2325-10-2
MDL NumberMFCD00064255

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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