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CAS: 2244-16-8
分子式: C10H14O
分子量: 150.22
沸点: 230-100℃
熔点: 88.9°C
中文名称: 
(S)-2-甲基-5-(1-甲基乙烯基)-2-环己烯-1-酮
S-(+)-香芹酮
右旋香芹酮
(+)-香芹酮
(S)-(+)-香芹酮
(S)-5-异丙烯基-2-甲基-2-环己烯酮
英文名称: 
2-methyl-5-(1-methylethenyl)-, (S)-2-Cyclohexen-1-one
(S)-(+)-p-mentha-8-dien-2-one
(+)-carvone
(S)-(+)-p-mentha-6,8-dien-2-one
(S)-carvone
(S)-d-p-mentha-6,8,(9)-dien-2-one
(S)-2-cyclohexen-1-on
(+)-carvon
d(+)-carvone
d-1-methyl-4-isopropenyl-6-cyclohexen-2-one
d-carvone
(S)-5-Isopropenyl-2-methyl-2-cyclohexenone
d-p-mentha-6,8,(9)-dien-2-one
(S)-(+)-5-Isopropenyl-2-methyl-2-cyclohexenone
2-Cyclohexen-1-one,2-methyl-5-(1-methylethenyl)-,(S)-
(S)-p-mentha-6,8-dien-2-one
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格
S792755MACKLIN右旋香芹酮10mM in DMSO185元/1ml;   咨询
储存:-20°C, 避光, 惰性气体
S804894MACKLIN右旋香芹酮97%54元/25ml;   168元/100ml;   750元/500ml;   2850元/2.5L;   咨询
储存:室温
状态:无色到黄色液体
折射率:n20/D 1.499
C0704TCI(S)-(+)-Carvone>98.0%(GC)530元/25ML;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C10H14O = 150.22
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN2042970
PubChem物质ID87565789
SDBS (AIST Spectral DB)6738
Merck Index (14)1874
MDL编号MFCD00062997

技术规格

Purity(GC)min. 98.0 %
Specific rotation [a]20/D+57.0 to +62.0 deg(neat)

物性(参考值)

沸点230 ℃
闪点93 ℃
比重0.96
比旋光度 [α]D61° (neat)
折射率1.50
水溶性不溶
溶解性(可与之混溶)
溶解性(可溶于)乙醚,氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H303 + H313 : 吞咽或皮肤接触可能有害。
H316 : 造成轻微皮肤刺激。
H317 : 可能造成皮肤过敏反应。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P272 : 受沾染的工作服不得带出工作场地。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P312 : 如感觉不适,呼叫急救中心/医生。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#OS8670000
934510J&K(S)-(+)-Carvone96%310元/25ML;   546元/100ML;   咨询

基本信息

分子式C10H14O
分子量150.22
沸点96-98
闪点97
密度0.96
折光率(n20D)1.4960-1.5000
比旋光度([α]20D)+50° to +62° (neat)
MDL编码MFCD00062997
Beilstein2042970
Merck14,1874
EINECS 编号218-827-2

安全信息

图形或危害标志
提示语Warning
危险说明H317
防范说明P261
P272
P280
P302+P352
P333+P313
P362+P364
WGK1
RTECSOS8670000
TSCA
L07130Alfa Aesar(S)-(+)-Carvone96%956元/25g;   2842元/100g;   咨询

应用
Carvones are used in the food and flavor industry. It is also used in air freshening products. Oils containing carvones are used in aromatherapy and alternative medicine. In organic synthesis, it is used as a starting material for the synthesis of terpenoid quassin natural product.

备注
Incompatible with strong oxidizing agents and strong reducing agents. Keep the container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00062997

EINECS
218-827-2

分子式
C10H14O

分子量
150.22

沸点
228-230°

闪点
93°(199°F)

密度
0.959

折射率
1.4980

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with diethyl ether, ethanol and chloroform. Immiscible with water.

Beilstein
2042970

Merck
14,1874

GHS危害和防范说明

Hazard Statements
H227
Combustible liquid.

Precautionary Statements
P210e-P280a-P370+P378a-P403+P235-P501a
Wear protective gloves and eye/face protection.In case of fire: Use for extinction: CO2, powder or water spray.Store in a well-ventilated place. Keep cool.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

RTECS
OS8670000

TSCA

C37784Alfa AesarD(+)-Carvone98%, synthetic821元/25ml;   2463元/100ml;   咨询

基本信息

Ref#
37784

MDL
62997

分子式
C10 H14 O

分子量
150.22

闪点
97

密度
0.956

C15068Alfa AesarD(+)-Carvone96%, natural802元/25g;   2280元/100g;   咨询

基本信息

Ref#
15068

MDL
62997

分子式
C10 H14 O

分子量
150.22

闪点
97

密度
0.956

形态
Liquid

22070Supelco(+)-Carvoneanalytical standard539.93元/1 ML;   994.47元/25 ML;   3552.89元/100 ML;   咨询

产品说明

一般描述

(+)-Carvone (S-carvone), is a monoterpene which has the ability to affect regulation of plant growth and development and microbial activity, it can also prevent sprouting in potato, through inhibition of the induction of phenylalanine ammonia-lyase (PAL) activity, thereby blocking suberisation.

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2042970
EC 号218-827-2
MDL编号MFCD00062997
PubChem化学物质编号329752243

产品性质

质量水平100
等级analytical standard
测定≥98.5% (sum of enantiomers, GC)
旋光性[α]20/D +61±2°, neat
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.499
bp228-230 ℃ (lit.)
密度0.960 g/mL at 20 ℃ (lit.)
application(s)agriculture
environmental
food and beverages
格式neat
SMILES stringCC(=C)[C@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
InChI keyULDHMXUKGWMISQ-VIFPVBQESA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P261 - P272 - P280 - P302 + P352 - P333 + P313 - P362 + P364
危险分类Skin Sens. 1A
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)204.1 °F - closed cup
闪点(C)95.6 ℃ - closed cup
个人防护装备Eyeshields, Gloves
W224928Sigma-AldrichD-Carvone≥96%, FG404.65元/;   566.48元/100 G;   1544.78元/1 KG;   5262.78元/5 KG;   咨询

产品说明

一般描述

D-Carvone is a monoterpene ketone that can be used as a flavoring agent. It occurs naturally in essential oil of caraway seeds and citrus fruits.

包装

100 g in poly bottle
1 kg in poly bottle
5 kg in poly drum

基本信息

经验(实验)分子式C10H14O
分子量150.22
FEMA编号2249
Beilstein2042970
EC 号218-827-2
欧洲委员会编号146
MDL编号MFCD00062997
PubChem化学物质编号24900949
Flavis编号7.146

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencyfollows IFRA guidelines
meets purity specifications of JECFA
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
FDA 21 CFR 117
测定≥96%
组成contains IFRA restricted Carvone
折射率n20/D 1.497 (lit.)
bp96-98 ℃/10 mmHg (lit.)
密度0.96 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查caraway; minty
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物carvone
SMILES stringCC(=C)[C@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
InChI keyULDHMXUKGWMISQ-VIFPVBQESA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P261 - P272 - P280 - P302 + P352 - P333 + P313 - P362 + P364
危险分类Skin Sens. 1A
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)204.1 °F - closed cup
闪点(C)95.6 ℃ - closed cup
个人防护装备Eyeshields, Gloves
435759Sigma-Aldrich(S)-(+)-Carvone96%336.16元/5 ML;   1115.22元/25 ML;   咨询

产品说明

一般描述

( S )-(+)-香芹酮是一种主要存在于香菜和小茴香籽油中的单萜烯,用于化妆品、食品和药物制剂中。

应用

(S)-(+)-香芹酮可作为起始原料合成:

  • (-)-Samaderine Y,一种五环的苦木素类化合物。
  • 降龙涎醚[(-)-Ambrox],一种类萜,是龙涎香香气的主要成分。
  • 3β-Acetoxydrimenin(一种倍半萜),通过氰化钾的共轭加成反应继以碱催化的Robinson环化反应制备而成。
  • 毒胡萝卜素家族成员,比如trilobolide、nortrilobolide和thapsivillosin F。

包装

5 mL in glass bottle
25 mL in poly bottle
( S )-(+)-香芹酮是一种主要存在于香菜和小茴香籽油中的单萜烯,用于化妆品、食品和药物制剂中。

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2042970
EC 号218-827-2
MDL编号MFCD00062997
PubChem化学物质编号24867255
NACRESNA.22

产品性质

质量水平100
测定96%
旋光性[α]23/D +55.0±7°, neat
折射率n20/D 1.497 (lit.)
bp96-98 ℃/10 mmHg (lit.)
密度0.96 g/mL at 25 ℃ (lit.)
SMILES stringCC(=C)[C@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
InChI keyULDHMXUKGWMISQ-VIFPVBQESA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P280
危险分类Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
8.18410Sigma-Aldrich(S)-(+)-Carvonefor synthesis271.71元/25 ML;   咨询

产品说明

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.958 - 0.962
Spec. rotation [α²0/D (undiluted): +57.0 - +62.0 °
Identity (IR): passes test

基本信息

经验(实验)分子式C10H14O
分子量150.22
MDL编号MFCD00062997
EC索引号218-827-2

产品性质

质量水平200
测定≥99.0% (GC)
效能3562 mg/kg LD50, oral (Rat)
bp228-230 ℃/1013 hPa
转变温度flash point 88 ℃ (DIN 51758)
溶解性 29-79 g/L
密度0.96 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
InChI keyULDHMXUKGWMISQ-VIFPVBQESA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P261 - P272 - P280 - P302 + P352 - P333 + P313 - P362 + P364
危险分类Skin Sens. 1A
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)204.1 °F - closed cup
闪点(C)95.6 ℃ - closed cup
PHL80240(+)-Carvonephyproof® Reference Substance3048.57元/100 MG;   咨询

产品说明

一般描述

This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG

法律信息

phyproof is a registered trademark of PhytoLab GmbH & Co. KG

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2042970
MDL编号MFCD00062997

产品性质

等级primary reference standard
产品线phyproof® Reference Substance
测定≥95.0% (GC)
形式liquid
manufacturer/tradenamePhytoLab
bp228-230 ℃ (lit.)
密度0.960 g/mL at 20 ℃ (lit.)
储存温度2-8℃
SMILES stringCC(=C)[C@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
InChI keyULDHMXUKGWMISQ-VIFPVBQESA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P280 - P302 + P352
危险分类Skin Sens. 1A
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)204.1 °F - closed cup
闪点(C)95.6 ℃ - closed cup
79245Supelco(+)-Carvonecertified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland1482.65元/100 mg;   咨询

产品说明

一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com.

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C10H14O
分子量150.22
Beilstein2042970
EC 号218-827-2
MDL编号MFCD00062997
PubChem化学物质编号329768335

产品性质

质量水平300
等级certified reference material
TraceCERT®
technique(s)HPLC: suitable
gas chromatography (GC): suitable
bp228-230 ℃ (lit.)
密度0.960 g/mL at 20 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
格式neat
储存温度−20℃
SMILES stringCC(=C)[C@H]1CC=C(C)C(=O)C1
InChI1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
InChI keyULDHMXUKGWMISQ-VIFPVBQESA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P280
危险分类Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)192.2 °F - closed cup
闪点(C)89 ℃ - closed cup
242575Fluorochem(S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone95%418元/25g;   1056元/100g;   咨询

基本信息

CAS Number2244-16-8
MDL NumberMFCD00062997
Density0.96

安全信息

图形或危害标志
危险性说明 H317: May cause an allergic skin reaction.
防范说明 P261: Avoid breathing .
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see . on this label).
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to .
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