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CAS: 2227217-19-6
分子式: C21H27O3P
分子量: 358.41
中文名称: 
(S)-3-(叔丁基)-4-(2,6-二甲氧基苯基)-2,2-二甲基-2,3-二氢苯并[d][1,3]氧磷杂环戊烷
英文名称: 
(S)-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
推荐供应商
货号品牌产品名称规格包装、参考价格
S938853MACKLIN(3S)-4-(2,6-二甲氧基苯基)-3-叔丁基-2,3-二氢-2,2-二甲基-1,3-苯并氧膦杂环97%,≥99% ee387元/25mg;   1162元/100mg;   5351元/500mg;   咨询
储存:2-8°C,密封,干燥
15-6880Strem(S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2,2-dimethyl-2,3-dihydrobenzo[d][1,3]oxaphosphole97% (>99% ee)750元/25mg;   2250元/100mg;   9000元/500mg;   咨询

Technical Notes: L igand used with

1.Palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.

2.NickeI catalyst for asymmetric intramolecular/intermolecular reductive addition.

References:

1. Org. Lett. 2012, 14 , 2258 2261

2.J. Am. Chem. Soc., 2014, 136, 570- 573

3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148

4.Adv. Synth. Catal. 2016, 358, 3522-3527

5.ACS Catal. 2018, 8, 10190-10209

6.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524

7.Org. Chem. Front. 2015, 2, 1322-1325

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