CAS 2222690-89-1; mesyl(2-(di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(ii),; mordalphos pd g3

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CAS:

2222690-89-1

分子式:

C₄₃H₅₅N₂O₄PPdS

分子量:

833.37

熔点:

245-250 °C

中文名称:

mesyl(2-(di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(ii),

(2-(di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(ii) methanesulfonate

英文名称:

mordalphos pd g3

mordalphos-g3-palladacycle

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货号

品牌

产品名称

规格

包装、参考价格

M958547

MACKLIN

甲磺酸盐(2-(二-1-金刚烷膦)吗啉苯)[2-(2′-氨基-1,1′-联苯)]钯(II)

98%

150元/100mg; 303元/250mg; 969元/1g;

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储存：2-8°C, 避光, 惰性气体
状态：白色至灰白色固体

46-0935

Strem

Methanesulfonato{N-[2-(di-1-adamantylphosphino)phenyl]morpholine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct

min. 98% [Mor-Dalphos Palladacycle Gen. 3]

1065元/250mg; 3225元/1g;

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Technical Note:

1. Palladium precatalyst for general c c and c N cross-coupling re actions:

a.Suzuki-Miyaura coupling reactions

b.Arylation reactions of primary amines, secondary amines, primary amides, phenols, alcohols, tert-butylacetate

792357

Sigma-Aldrich

MorDalphos Pd G3

474.72元/250 MG; 901.98元/500 MG; 2339.79元/2 G; 4814.7元/5 G;

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产品说明

一般描述

MorDalphos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. MorDalphos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

包装

250, 500 mg in glass bottle
2, 5 g in glass bottle

基本信息

经验(实验)分子式	C₄₃H₅₅N₂O₄PPdS
分子量	833.37
MDL编号	MFCD28137452
PubChem化学物质编号	329768328
NACRES	NA.22

产品性质

质量水平	100
特点	generation 3
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst reaction type: Cross Couplings
mp	245-250 ℃
官能团	phosphine
SMILES string	NC1=C(C=CC=C1)C2=C([Pd]OS(=O)(C)=O)C=CC=C2.P([C@]34C[C@@H](C[C@@H](C4)C5)C[C@@H]5C3)([C@@]6(C[C@@H](C7)C8)C[C@H]7C[C@H]8C6)C9=CC=CC=C9N%10CCOCC%10
InChI	1S/C30H42NOP.C12H10N.CH4O3S.Pd/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h1-4,21-26H,5-20H2;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key	XDLJAOATDSJDKP-UHFFFAOYSA-M

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

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