CAS 220114-03-4; 二氯化[(S)-2,2'-双[二(3,5-二甲苯基)膦]-1,1'-联萘基][(s,s)-1,2-二苯乙烯基二胺]钌(ii); rucl<sub>2</sub>[(S)-xylbinap][(s,s)-dpen]

CAS:

220114-03-4

分子式:

C₆₆H₆₄Cl₂N₂P₂Ru

分子量:

1119.17

中文名称:

二氯化[(S)-2,2'-双[二(3,5-二甲苯基)膦]-1,1'-联萘基][(s,s)-1,2-二苯乙烯基二胺]钌(ii)

英文名称:

rucl₂[(S)-xylbinap][(s,s)-dpen]

dichloro[(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(s,s)-1,2-diphenylethylenediamine]ruthenium(ii)

用途:

电池材料

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

R868225

MACKLIN

RuCl2[(S)-xylbinap][(S,S)-dpen]

≥95%

508元/200mg;

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储存：室温

R0134

TCI

RuCl₂[(S)-xylbinap][(S,S)-dpen]

555元/200MG; 2080元/1G;

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基本信息

分子式/分子量	C₆₆H₆₄Cl₂N₂P₂Ru = 1119.17
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
包装和容器	200MG-带有塑料内管的玻璃瓶 (查看图片)
PubChem物质ID	253659928
MDL编号	MFCD09753030

技术规格

Appearance	Yellow to Brown to Dark green powder to crystal
IR	to pass test

44-0224

Strem

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen]

960元/250mg; 2642元/1g; 7110元/5g;

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Technical Notes:

1.See 44-0210.

2.Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes .

3.Asymmetic hydrogenation of imines .

4.Catalysts for deracemization of benzylic alcohols.

References:

1.Angew Chem. Int. Ed., 2001, 40, 40. (review)

2.Adv.Synth. Catal.2001. 343, 369.

3.Adv. Synth. Catal., 2003, 345, 195.

4.Chem. Commun. 2007, 2608.