Technical Notes :

1. Catalyst for the asymmetric ring-opening of mes o-epoxides and for the kinetic res olution of terminal epoxides. 2. Precatalyst for as ymmetric Diels -Alder and hetero Diels-Alder reactions.

3.Catalyst for copolymerization of CO2 and epoxides

4. Catalyst for enantios elective alkylation of tributyltin enolates .

5. Enantioselective addition of Me2Zn to aldehydes .

6.Enantios elective intramolecular addition of tertiary enamides to ketones.

7.Asymmetric iodocyclization.

8.Catalytic intermolecular linear allylic C-H animation.

9. Cocatalyst for enantios elective ring opening of epoxides with fluoride.

References:

1.Acc. Chem. Res., 2000, 33, 421. (review)

2.J.Am. Chem. Soc., 2000, 122, 7843.

3.J.Am. Chem.1998 63,403.

4. Acc. Chem. Res., 2004, 37, 836.

5. (a) J. Am. Chem. Soc., 2005, 127, 62. (b) Angew. Chem. Int. Ed., 2007, 46, 3701.