Technical Notes:

1. L igands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pe nding Stanford l Jniversity patents.

2.Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers .

References:

1.J. Am. Chem. Soc, 1998 120, 1 104.

2.J.amChem. Soc., 2002, 124, 14320.

3.J. Am. Chem. Soc., 2002, 124, 7256.

4.For a review, see e-Encyclopedia or Reagents for Organic Synthesis

"(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2- pyridinecarboxamide)", 2014.

基本信息

分子量
324.38