CAS 213843-90-4; (3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

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CAS:

213843-90-4

分子式:

C₃₃H₃₄NO₄P

分子量:

539.60

沸点:

569.804°C

熔点:

218-221 ℃

英文名称:

(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

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货号

品牌

产品名称

规格

包装、参考价格

详情

R857213

MACKLIN

(3aR,8aR)-(2,2-二甲基-4,4,8,8-四苯基-四氢-[1,3]二噁唑并[4,5-e][1,3,2]二噁膦杂庚英-6-基)二甲胺

98%

135元/100mg; 653元/500mg;

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储存：室温,干燥
状态：白色到棕褐色粉末,晶体和/或块状

15-1505

Strem

(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

min. 98%

1474元/100mg; 6360元/500mg;

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Technical Notes:

1. Monodendate ligand for the enantioselective intramolecular reaction of prochiral cyclohexadienones .

2.Ligand use in the palladium-catalyzed, enantioselective diboration of allenes.

3.Enantioselective Rh-catalyzed2+2+2 cycloaddition of alkynes and isocyanates.

4.Palladium-catalyzed enantioselective C-H arylation.

5.Palladium-catalyzed dynamic kinetic cross-coupling

6.Palladium-catalyzed enantioselective C-H arylation.

15-5130

Strem

(11aR)-(+)-10,11,12,13-Tetrahydro-5-(1,1-dimethylethyl)diindeno[7,1-de,1',7'-fg)[1.3.2] dioxaphosphocin

97%

1050元/25mg; 2919元/100mg;

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Technical Note:

1.Chiral ligand for the rhodium-catalyzed, asymmetric hydrogenation of enamines.

Reference:

1. J. Am. Chem Soc., 2006, 128, 117 74.

Y10534

Alfa Aesar

(R,R)-TADDOL-PNMe2

1314元/100mg; 3116元/250mg; 11429元/1g;

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基本信息

分子量
539.61

665460

Sigma-Aldrich

(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

96%

1203.21元/100 MG; 4186.06元/500 MG;

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产品说明

应用

DSM MonoPhos Family of Highly Efficient Privileged Ligands
亚磷酰胺配体，用于丙烯基硼酸酯的铱催化不对称烯丙基化反应。还用于二乙基锌的铜催化不对称共轭加成至氨基酸衍生的 α,β-不饱和亚胺。

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

法律信息

经 DSM 授权销售，仅供研究之用。

基本信息

经验(实验)分子式	C₃₃H₃₄NO₄P
分子量	539.60
MDL编号	MFCD04117685
PubChem化学物质编号	24884738
NACRES	NA.22

产品性质

测定	96%
mp	218-221 ℃
SMILES string	CN(C)P1OC([C@@H]2OC(C)(C)O[C@H]2C(O1)(c3ccccc3)c4ccccc4)(c5ccccc5)c6ccccc6
InChI	1S/C33H34NO4P/c1-31(2)35-29-30(36-31)33(27-21-13-7-14-22-27,28-23-15-8-16-24-28)38-39(34(3)4)37-32(29,25-17-9-5-10-18-25)26-19-11-6-12-20-26/h5-24,29-30H,1-4H3/t29-,30-/m1/s1
InChI key	DRPNADVMTMEWQY-LOYHVIPDSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

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