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CAS: 2136-75-6
分子式: C20H17OP
分子量: 304.32
熔点: 185-188℃
中文名称: 
三苯基磷
英文名称: 
(triphenylphosphoranylidene)acetaldehyde
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货号品牌产品名称规格包装、参考价格详情
T821421MACKLIN甲酰甲撑基三苯基膦97%20元/1g;   25元/5g;   43元/25g;   159元/100g;   703元/500g;   3383元/2.5kg;   展开
储存:2~8°C
状态:浅黄色到橙色到暗橙色和微棕色到棕色和红色到暗红色和棕色-橙色和橙棕色固体
T2001TCI(Triphenylphosphoranylidene)acetaldehyde>98.0%(HPLC)490元/5G;   1990元/25G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C20H17OP = 304.33
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN523797
PubChem物质ID87577692
MDL编号MFCD00006994

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 95.0 %

物性(参考值)

熔点198 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
440598J&K(Triphenylphosphoranylidene)acetaldehyde97%265元/5G;   875元/25G;   展开

基本信息

分子式C20H17OP
分子量304.33
熔点185-188
MDL编码MFCD00006994
Beilstein523797
EINECS 编号218-375-6
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P280
P302+P352
P305+P351+P338
WGK3
TSCA
A11709Alfa Aesar(Formylmethylene)triphenylphosphorane97%, may cont. up to ca 3% water1330元/10g;   2470元/25g;   9106元/100g;   展开

应用
(Formylmethylene)triphenylphosphorane is used as Wittig reagent. It is also used as Pharmaceutical Intermediates. It is employed as raw material in organic Synthesis, Agrochemicals.

备注
Air Sensitive. Store at -20?°C. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00006994

EINECS
218-375-6

分子式
(C6H5)3P=CHCHO

分子量
304.33

熔点
183-188°

灵敏度
Keep Cold. Air Sensitive.

形态
Powder

溶解性
Soluble in Chloroform, Methanol.

Beilstein
523797

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C30749Alfa Aesar(Triphenylphosphoranylidene)acetaldehyde97%1034元/5g;   3880元/25g;   15405元/100g;   展开

基本信息

Ref#
30749

MDL
6994

分子式
C20 H17 O P

分子量
304.33

280933Sigma-Aldrich(Triphenylphosphoranylidene)acetaldehyde95%450.44元/5 G;   1639.35元/25 G;   展开

产品说明

包装

5, 25 g in glass bottle

应用

用于将醛和酮转化为二碳同系化 α,β-不饱和羰基化合物的 Wittig 试剂。

基本信息

线性分子式HCOCH=P(C6H5)3
分子量304.32
Beilstein523797
EC 号218-375-6
MDL编号MFCD00006994
PubChem化学物质编号24856960
NACRESNA.22

产品性质

质量水平200
测定95%
reaction suitabilityreaction type: C-C Bond Formation
mp185-188 ℃ (lit.)
SMILES string[H]C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C20H17OP/c21-16-17-22(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-17H
InChI keyCQCAYWAIRTVXIY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
317855FluorochemFormylmethylenetriphenylphosphorane97%308元/5g;   550元/10g;   814元/25g;   2420元/100g;   展开

基本信息

CAS Number2136-75-6
MDL NumberMFCD00006994
Melting Point185 - 188 ℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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