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CAS: 21170-10-5
分子式: C10H14O2
分子量: 166.21
熔点: 219-221℃
英文名称: 
cis-1,5-dimethylbicyclo[3.3.0]octane-3,7- dione
cis-1,5-Dimethylbicyclo[3,3,0]octane-3,7-dione
用途: Olefination of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione with (carbethoxyethylidene)triphenylphospharane under controlled microwave heating has been investigated. It reacts with carbon disulfide, strong base and an alkylating agent in dipolar aprotic solvents to yield racemic mixtures of 2-dialkylthio-methylene compounds.
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D921788MACKLIN顺-1,5-二甲基二环[3.3.0]辛烷-3,7-二酮≥98%463元/1g;   展开
储存:室温
状态:固体
220841Sigma-Aldrichcis-1,5-Dimethylbicyclo[3.3.0]octane-3,7-dione≥98%768.47元/1 G;   展开

产品说明

一般描述

Olefination of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione with (carbethoxyethylidene)triphenylphospharane under controlled microwave heating has been investigated. It reacts with carbon disulfide, strong base and an alkylating agent in dipolar aprotic solvents to yield racemic mixtures of 2-dialkylthio-methylene compounds.

包装

1 g in glass bottle

基本信息

经验(实验)分子式C10H14O2
分子量166.22
EC 号244-255-8
MDL编号MFCD00003772
PubChem化学物质编号24853195
NACRESNA.22

产品性质

质量水平100
测定≥98%
mp228-230 ℃ (lit.)
SMILES stringC[C@]12CC(=O)C[C@@]1(C)CC(=O)C2
InChI1S/C10H14O2/c1-9-3-7(11)5-10(9,2)6-8(12)4-9/h3-6H2,1-2H3/t9-,10+
InChI keyKGZWVKASYOPUET-AOOOYVTPSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
321487Fluorochemcis-3a,6a-Dimethyltetrahydropentalene-2,5(1H,3H)-dione95%704元/1g;   2816元/5g;   展开

基本信息

CAS Number21170-10-5
MDL NumberMFCD00003772
Melting Point228 - 230 ℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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