CAS 2102544-35-2; [(2-{bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(ii) methanesulfonate; jackiephos pd g3

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CAS:

2102544-35-2

分子式:

C₅₂H₅₀F₁₂NO₅PPdS

分子量:

1166.40

熔点:

195-197 °C

中文名称:

[(2-{bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(ii) methanesulfonate

英文名称:

jackiephos pd g3

jackiephos-pd-g3

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货号

品牌

产品名称

规格

包装、参考价格

J959515

MACKLIN

[(2-双[3,5-双(三氟甲基)苯基]膦-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯)-2-(2'-氨基-1,1'-联苯)]钯(II)甲磺酸盐

≥95%

329元/100mg; 547元/250mg; 1365元/1g;

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储存：2-8°C, 避光, 惰性气体
状态：固体

46-0340

Strem

Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)

min. 98%

1725元/100mg; 6930元/500mg; 24270元/2g;

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Technical Notes:

1. L igand used in the Pd-catalyzed coupling of aryl nonaflates and triflates with secondary amides.

2. L igand used in the Pd- catalyzed coupling of aryl nonaflates and triflates with secondary ureas, carbamates, and

sulfonamides.

3.Ligand used in the Pd-catalyzed coupling of aryl chlorides with secondary amides, carbamates, and sulfonamides. .

4.L igand used in the Pd-catalyzed coupling of se condary alkyl stannanes with aryl halides.

References: 1: J: Am. Chem, Soc., 2009.131, 16720. 2. Chem. Sci 2011 2 27-50 3.Nat.Chem.，2013，5，607

762830

Sigma-Aldrich

JackiePhos Pd G3

95%

1394.21元/100 MG; 4829.76元/500 MG; 5006.08元/1 G; 20593.9元/5 G;

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产品说明

应用

JackiePhos Pd G3 can be used as a palladium precatalyst in Stille cross-coupling reaction between organostannane and ary halides.

包装

1, 5 g in glass bottle
100, 500 mg in glass bottle

基本信息

经验(实验)分子式	C₅₂H₅₀F₁₂NO₅PPdS
分子量	1166.40
MDL编号	MFCD22572672
PubChem化学物质编号	329767007
NACRES	NA.22

产品性质

质量水平	100
测定	95%
特点	generation 3
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst reaction type: Cross Couplings
mp	195-197 ℃ (decomposition)
官能团	phosphine
SMILES string	CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.COc3ccc(OC)c(c3P(c4cc(cc(c4)C(F)(F)F)C(F)(F)F)c5cc(cc(c5)C(F)(F)F)C(F)(F)F)-c6c(cc(cc6C(C)C)C(C)C)C(C)C
InChI	1S/C39H37F12O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-21H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key	LLXGRQGGARSAOC-UHFFFAOYSA-M

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

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