CAS 2089424-11-1; (S)-n-(1-(3' ,5'-二-叔-丁基-[1,1'-联苯]-2-基)-2-(二苯基膦基)乙基)-3,5-二(三氟甲基)苯甲酰胺; (S)-n-(1-(3',5'-di-tert-butyl-[1,1'-biphenyl]-2-yl)-2-(diphenylphosphanyl)ethyl)-3,5-bis(trifluoromethyl)benzamide

CAS:

2089424-11-1

分子式:

C₄₃H₄₂F₆NOP

分子量:

733.8

中文名称:

(S)-n-(1-(3' ,5'-二-叔-丁基-[1,1'-联苯]-2-基)-2-(二苯基膦基)乙基)-3,5-二(三氟甲基)苯甲酰胺

英文名称:

(S)-n-(1-(3',5'-di-tert-butyl-[1,1'-biphenyl]-2-yl)-2-(diphenylphosphanyl)ethyl)-3,5-bis(trifluoromethyl)benzamide

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货号

品牌

产品名称

规格

包装、参考价格

详情

N915539

MACKLIN

N-[(1S)-1-[3',5'-双(叔丁基)(1,1'-联苯)]-2-(二苯基膦)乙基]-3,5-二(三氟甲基)苯甲酰胺

98%

233元/10mg;

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储存：室温
状态：固体

9026028

J&K

(S)-N-(1-(3',5'-Di-tert-butyl-[1,1'-biphenyl]-2-yl)-2-(diphenylphosphanyl)ethyl)-3,5-bis(trifluoromethyl)benzamide

97%

3400元/100MG;

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基本信息

分子式	C₄₃H₄₂F₆NOP
分子量	733.76

15-8508

Strem

N-[(1S)-1-[3',5'-Bis(1,1-dimethylethyl)[1,1'-biphenyl]-2-yl]-2-(diphenylphosphino)ethyl]-3,5-bis(trifluoromethyl)-benzamide

95%

3060元/50mg;

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Technical Notes:

1.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1 ,3-dienes with vinyl ketones.

2.Catalyst for the enantioselective 3+2 cycloadditions of v-substituted allenoates with ß-perfluoroalkyl enones.

3.Phosphine catalyst for difunctionalization of ß-fluoroalkyl a, ß-Enones to generate ß-amino a-diazo carbonyl compounds .

References:

1.Org. L ett.2017, 19, 1710.

2.Chem. Sci., 2017, 8, 4660

3.Angew. Chem. Int. Ed. 2018, 57, 15787.