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CAS: 20780-53-4
分子式: C8H8O
分子量: 120.15
沸点: 194℃
熔点: -37-90℃
中文名称: 
(R)-(+)-环氧乙苯
苯基环氧乙烷
英文名称: 
(epoxyethyl)-, (R)-Benzene
(R)-(Epoxyethyl)benzene
R-Phenyloxirane
(R)-benzen
(R)-styrene oxide
(R)-2-phenyl-oxirane
Benzene,(epoxyethyl)-,(R)-
推荐供应商
货号品牌产品名称规格包装、参考价格
R831394MACKLIN(R)-环氧苯乙烷97%,ee97%59元/1g;   199元/5g;   899元/25g;   2699元/100g;   咨询
储存:2~8℃
状态:无色到浅黄色液体
R799498MACKLIN(R)-环氧苯乙烷98%92元/1g;   319元/5g;   1132元/25g;   咨询
储存:室温
S0516TCI(R)-Styrene Oxide>96.0%(GC)785元/5G;   2750元/25G;   咨询

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C8H8O = 120.15
外观与形状(20℃)液体
Reaxys-RN1984
PubChem物质ID253662332
MDL编号MFCD00066210

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 96.0 %
Specific rotation [a]20/D+31.0 to +34.0 deg(neat)

物性(参考值)

沸点194 ℃
闪点77 ℃
比重1.05
比旋光度 [α]D33° (neat)
折射率1.54

安全信息

图形或危害标志
信号词危险
危险性说明H311 : 皮肤接触会中毒。
H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H361 : 怀疑对生育能力或胎儿造成伤害。
H373 : 长期或反复接触可能损害器官。
H317 : 可能造成皮肤过敏反应。
H341 : 怀疑可造成遗传性缺陷。
H350 : 可能致癌。
H336 : 可能造成昏昏欲睡或眩晕。
H401 : 对水生生物有毒。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#CZ9625010

运输信息

UN编号UN2810
类别6.1
包装类别 III
监管条件代码(*)
B21245Alfa Aesar(R)-(+)-Styrene oxide98%670元/1g;   2860元/5g;   7201元/25g;   咨询

应用
It is used to produce a homologated epoxide as part of a synthetic approach to (+)-allosedamine. It is the main metabolite of styrene, catalyzed by epoxide hydrolase.

备注
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00066210

分子式
C8H8O

分子量
120.15

沸点
194°

闪点
74°(165°F)

密度
1.051

折射率
1.5350

灵敏度
Keep Cold.

形态
Liquid

溶解性
Insoluble in water.

Beilstein
1984

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H312-H319-H350
Combustible liquid.Harmful in contact with skin.Causes serious eye irritation.May cause cancer.

Precautionary Statements
P210e-P201-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
45-21-36
May cause cancer.Harmful in contact with skin.Irritating to eyes.

安全等级
53-45
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
CZ9625010

TSCA

C24055Alfa Aesar(R)-Styrene Oxide95%, 95% ee921元/1g;   2039元/5g;   6776元/25g;   咨询

基本信息

Ref#
24055

MDL
66210

分子式
C8 H8 O

分子量
120.15

闪点
79

密度
1053

形态
Clear colourless liquid

安全信息

危险等级
6.1

包装组
III

540099Sigma-Aldrich(R)-(+)-Styrene oxide97%, optical purity ee: 97% (GLC)735.19元/5 G;   咨询

产品说明

应用

Used to produce a homologated epoxide as part of a synthetic approach to (+)-allosedamine.
(R)-(+)-Styrene oxide can be used:

  • As a chiral initiator in the synthesis of 5-pyrimidyl alkanol from its corresponding aldehyde using diisopropylzinc.
  • As a substrate in the stereoselective intermolecular O-alkylation of phenols with epoxides via Friedel–Crafts-type reaction.
  • As a substrate in the ring-opening reactions of epoxides with alcohols, carboxylic acids, and thiols using the AlPW12O40 catalyst.

包装

5 g in glass bottle
25 g in poly bottle

法律信息

经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。

基本信息

经验(实验)分子式C8H8O
分子量120.15
Beilstein1984
MDL编号MFCD00066210
PubChem化学物质编号24878440
NACRESNA.22

产品性质

质量水平100
测定97%
旋光性[α]20/D +33°, neat
光学纯度ee: 97% (GLC)
expl. lim.~22 %
折射率n20/D 1.534 (lit.)
bp89-90 ℃/23 mmHg (lit.)
密度1.051 g/mL at 25 ℃ (lit.)
SMILES stringC1O[C@@H]1c2ccccc2
InChI1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2/t8-/m0/s1
InChI keyAWMVMTVKBNGEAK-QMMMGPOBSA-N

安全信息

象形图GHS07GHS08
警示用语:Danger
危险声明H312 - H319 - H350
预防措施声明P202 - P264 - P280 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Dermal - Carc. 1B - Eye Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)176.0 °F - closed cup
闪点(C)80 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
221507Fluorochem(R)-2-Phenyloxirane95%374元/1g;   968元/5g;   4378元/25g;   14146元/100g;   咨询

基本信息

CAS Number20780-53-4
MDL NumberMFCD00066210
Boiling Point194℃
Density1.05

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H227: Combustible liquid
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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