CAS 20769-85-1; 2-溴异丁酰溴; 2-bromoisobutyrylbromide

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货号

品牌

产品名称

规格

包装、参考价格

B802437

MACKLIN

2-溴异丁酰溴

98%

43元/25g; 98元/100g; 297元/500g; 1289元/2.5kg;

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储存：室温
状态：无色到淡黄色到浅棕色液体
折射率：n20/D 1.507(lit.)

B0607

TCI

2-Bromoisobutyryl Bromide

>98.0%(GC)

185元/25G; 405元/100G; 895元/500G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₄H₆Br₂O = 229.90
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	1746128
PubChem物质ID	87563621
SDBS (AIST Spectral DB)	3668
MDL编号	MFCD00000122

技术规格

Appearance	Colorless to Light yellow clear liquid
Purity(GC)	min. 98.0 %
Purity(Argentometric Titration)	min. 97.0 %

物性(参考值)

沸点	164 ℃
比重	1.87
折射率	1.51

安全信息

图形或危害标志
信号词	危险
危险性说明	H314 : 造成严重皮肤灼伤和眼损伤。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3265
类别	8
包装类别	III
监管条件代码(*)

543662

J&K

2-Bromo-2-methylpropionyl Bromide

98%

77元/25G; 253元/100G; 818元/500G;

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基本信息

分子式	C₄H₆Br₂O
分子量	229.90
沸点	162-164
闪点	113
密度	1.86
折光率(n20D)	1.5070 - 1.5120
MDL编码	MFCD00000122
Beilstein	1746128
EINECS 编号	244-017-3
存储条件	Corrosives

安全信息

图形或危害标志
提示语	Danger
危险说明	H302 H314
防范说明	P280 P305+P351+P338 P310
UN号码	3265
危险分类	8
包装等级	II
WGK	3

B24249

Alfa Aesar

2-Bromoisobutyryl Bromide

97%

254元/25g; 453元/100g; 1652元/500g;

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应用
2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.

备注
Moisture sensitive. Incompatible with strong oxidizing agents and strong alkalis.

基本信息

MDL
MFCD00000122

EINECS
244-017-3

分子式
C₄H₆Br₂O

分子量
229.91

沸点
160-162°

闪点
>110°(230°F)

密度
1.860

折射率
1.5095

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Miscible with acetone and carbon disulfide.

Beilstein
1746128

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
14-34
Reacts violently with water.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
是

C40309

Alfa Aesar

2-Bromo-2-methylpropionyl Bromide

98%

785元/5g; 1241元/100g; 5257元/500g;

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基本信息

Ref#
40309

MDL
122

分子式
C4 H6 Br2 O

分子量
229.9

密度
1.86

安全信息

危险等级
8

包装组
II

252271

Sigma-Aldrich

α-Bromoisobutyryl bromide

98%

823.57元/100 G; 1228.24元/500 G;

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产品说明

应用

α-溴异丁酰溴已用于：

作为原子转移自由基聚合(ATRP)引发剂，用于氧化石墨烯表面上羟基的官能化
形成一个 N保护的卤代二烯酰胺，在铜(I)和叔胺存在下提供四元和五元内酰胺
通过与低聚己内酯二醇反应制备聚己内酯大分子引发剂通过与固定在外表面的ATRP引发剂反应制备介孔二氧化硅纳米粒子

包装

100, 500 g in glass bottle

基本信息

线性分子式	(CH₃)₂CBrCOBr
分子量	229.90
Beilstein	1746128
EC 号	244-017-3
MDL编号	MFCD00000122
PubChem化学物质编号	24855196
NACRES	NA.22

产品性质

质量水平	100
测定	98%
形式	liquid
折射率	n20/D 1.507 (lit.)
bp	162-164 ℃ (lit.)
密度	1.86 g/mL at 25 ℃ (lit.)
SMILES string	CC(C)(Br)C(Br)=O
InChI	1S/C4H6Br2O/c1-4(2,6)3(5)7/h1-2H3
InChI key	YOCIJWAHRAJQFT-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类	Eye Dam. 1 - Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	230.0 °F
闪点(C)	> 110 ℃
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

098961

Fluorochem

alpha-Bromoisobutyryl bromide

99%

220元/1g; 242元/5g; 616元/100g; 2772元/500g;

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基本信息

CAS Number	20769-85-1
MDL Number	MFCD00000122
Density	1.86

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P330: Rinse mouth. P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.