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CAS: 20765-98-4
分子式: Cl3Rh.xH2O
分子量: 263.31
熔点: 100-450℃
中文名称: 
三氯化铑水合物
英文名称: 
Rhodium trichloride hydrate
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货号品牌产品名称规格包装、参考价格详情
R798907MACKLIN三氯化铑(III),三水合物≥99.9% trace metals basis1499元/250mg;   3899元/1g;   12000元/5g;   展开
储存:室温, 密封, 干燥
状态:红色到黑色晶体
R817275MACKLIN三氯化铑(III),三水合物Rh 38.5-42.5%1399元/200mg;   4898元/1g;   17146元/5g;   展开
储存:室温,干燥,密封
状态:红色到黑色粉末和/或晶体
R796665MACKLIN三氯化铑(III),三水合物99.95% metals basis1625元/250mg;   3999元/1g;   展开
储存:室温, 密封, 干燥
45-1880StremRhodium(III) chloride hydrate38-41% Rh3300元/250mg;   9175元/1g;   39600元/5g;   158400元/25g;   展开

Technical Notes:

1.Catalyst in conjunction with "pybox" for the asymmetric hydrosilylation of ketones.

2. C-C bond forming reactions.

References:

1.Catalytic Asymmetric Synthesis, 1993, Ch 6, 303.

2.Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 6, 4409.

3.Chem. Commun., 2003, 2438.

4.Org. L ett., 2003, 5, 893.

5.Chem. Commun., 2004, 1192.

011032Alfa AesarRhodium(III) chloride hydrateRh 38.0-45.5%0元/0.25g;   0元/1g;   0元/5g;   0元/25g;   展开

应用
Rhodium(III) chloride hydrate is used as a catalyst to prepare acetic acid. It is also used as a catalyst for reduction, oxidation of alkenes, hydration of acetylene and isomerization of alkenes. It is involved in the hydrosilylation of alfa,beta-unsaturated esters to form dimethylketene trimethylsilyl acetals.

备注
Incompatible with strong oxidizing agents, strong acids and bases.

基本信息

MDL
MFCD00149839

分子式
RhCl3?xH2O

分子量
209.26(anhy)

熔点
100° dec.

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in alcohol and water. Slightly soluble in acetone.

Merck
14,8188

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H318-H341
May be corrosive to metals.Harmful if swallowed.Causes serious eye damage.Suspected of causing genetic defects.

Precautionary Statements
P201-P280-P305+P351+P338-P310a-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-41-68
Harmful if swallowed.Risk of serious damage to eyes.Possible risk of irreversible effects.

安全等级
26-36/37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

043702Alfa AesarRhodium(III) chloride hydratePremion庐, 99.99% (metals basis)0元/1g;   0元/5g;   展开

应用
Rhodium(III) chloride hydrate is used as a catalyst for the conversion of methane to acetic acid, isomerization of alkenes, reduction of aromatic rings and hydration of acetylene. It is involved in the hydrosilylation of alfa,beta-unsaturated esters to form dimethylketene trimethylsilyl acetals. It plays an important role as a catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids.

备注
Hygroscopic. Incompatible withoxidizing agents.

基本信息

MDL
MFCD00149839

EINECS
233-165-4

分子式
RhCl3•xH2O

分子量
209.26(anhy)

熔点
100° dec.

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water and alcohol. Slightly soluble in acetone.

Merck
14,8188

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H318-H341
May be corrosive to metals.Harmful if swallowed.Causes serious eye damage.Suspected of causing genetic defects.

Precautionary Statements
P201-P280-P305+P351+P338-P310a-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-41-68
Harmful if swallowed.Risk of serious damage to eyes.Possible risk of irreversible effects.

安全等级
26-36/37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C19552Alfa AesarRhodium(III) chloride hydrate38% Rh13583元/1g;   55801元/5g;   展开

基本信息

Ref#
19552

MDL
149839

分子式
Cl3 Rh . x H2 O

分子量
209.26

安全信息

危险等级
8

包装组
III

206261Sigma-AldrichRhodium(III) chloride hydrateRh 38-40 %2344.16元/250 MG;   8516.25元/1 G;   36907.9元/5 G;   52473.7元/10 G;   116873元/25 G;   展开

产品说明

包装

250 mg in glass bottle
1, 5, 10, 25 g in glass bottle

应用

用于甲烷直接转化为乙酸的催化剂。
用于肉桂醛共轭还原的催化剂,随后与芳基硼酸进行交叉偶联反应。
用于烯烃异构化、芳环还原、烯烃氧化、乙炔水合、α,β-不饱和酯硅氢化生成二甲基烯酮三甲基硅缩醛的催化剂。

基本信息

线性分子式RhCl3 · xH2O
分子量209.26 (anhydrous basis)
EC 号233-165-4
MDL编号MFCD00149839
PubChem化学物质编号24852390
NACRESNA.22

产品性质

质量水平200
形式powder or crystals
组成Rh, 38-40%
reaction suitabilitycore: rhodium
reagent type: catalyst
mp100 ℃ (dec.) (lit.)
SMILES stringO.Cl[Rh](Cl)Cl
InChI1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChI keyHSSMNYDDDSNUKH-UHFFFAOYSA-K

安全信息

象形图GHS05GHS07GHS08GHS09
警示用语:Danger
危险声明H290 - H302 - H318 - H341 - H410
预防措施声明P202 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Muta. 2
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
520772Sigma-AldrichRhodium(III) chloride hydratecrystalline, ≥99.9% trace metals basis4852.47元/1 G;   23038.1元/5 G;   展开

产品说明

应用

氯化铑(III)水合物 (RhCl3. xH2O) 可用作制备以下物质的金属前体:

  • 用于费托−(FT) 合成的二氧化硅负载铑-钴 (Rh-Co) 催化剂(双金属催化剂)
  • 用于酮的不对称还原的铑 (III) 催化剂,N-2-(2,3,4,5 四甲基l环戊二烯基)苄基-(l)-去甲基麻黄碱氯化铑 (III)
  • 用于1-辛烯的加氢甲酰化的Rh@CTF(共价三嗪骨架)催化剂

包装

1, 5 g in glass bottle

基本信息

线性分子式RhCl3 · xH2O
分子量209.26 (anhydrous basis)
EC 号233-165-4
MDL编号MFCD00149839
PubChem化学物质编号24874167

产品性质

质量水平100
测定≥99.9% trace metals basis
形式crystalline
组成Rh, 38-43.5%
reaction suitabilitycore: rhodium
reagent type: catalyst
mp100 ℃ (dec.) (lit.)
SMILES stringO.Cl[Rh](Cl)Cl
InChI1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChI keyHSSMNYDDDSNUKH-UHFFFAOYSA-K

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H290 - H302 - H318
预防措施声明P234 - P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
450286Sigma-AldrichRhodium(III) chloride hydrate99.95% trace metals basis2247.47元/250 mg;   5738.6元/1 g;   展开

产品说明

应用

本品已被用作Rh颗粒的前体,用于研究Rh对水-气体系的影响。

包装

250 mg in glass insert
1 g in glass bottle

基本信息

线性分子式RhCl3 · xH2O
分子量209.26 (anhydrous basis)
EC 号233-165-4
MDL编号MFCD00149839
PubChem化学物质编号24868236
NACRESNA.23

产品性质

质量水平100
测定99.98% trace metals basis
形式crystalline
组成Rh, 40%
杂质≤ 250.0  ppm Trace Metal Analysis
mp100 ℃ (dec.) (lit.)
SMILES stringO.Cl[Rh](Cl)Cl
InChI1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChI keyHSSMNYDDDSNUKH-UHFFFAOYSA-K

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H318
预防措施声明P280 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
235636FluorochemRhodium(III) chloride hydrate95%1430元/250mg;   4400元/1g;   18150元/5g;   展开

基本信息

CAS Number20765-98-4
MDL NumberMFCD00149839

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
防范说明 P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P501: Dispose of contents/container to local regulations.
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