CAS 205319-06-8; 双(二苯基膦苯基醚)二氯化钯(ii); dichloro[bis(diphenylphosphinophenyl)ether]palladium(ii)

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D808205

MACKLIN

双(二苯基膦苯基醚)二氯化钯(II)

95%

56元/250mg; 205元/1g; 1016元/5g;

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储存：2~8°C
状态：白色到黄色到橙色到棕色粉末/晶体

46-0463

Strem

Dichloro{bis[2-(diphenylphosphino)phenyl]ether}palladium(II)

98%

1065元/1g; 4395元/5g;

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Technical Notes:

1.Stereoretentive palladium-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.

2. Highly selective reactions of unbiased alkenyl halid es: N eg ishi-Plus couplings.

References:

1.Org. L ett., 2014, 16, 4066.

2. Or. Lett.. 2011, 13, 3822.

044977

Alfa Aesar

Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II)

Pd 13% min

3065元/1g; 8114元/5g;

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应用
Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) is used as a catalyst for cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z,E dienes.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD09953446

分子式
C₃₆H₂₈Cl₂OP₂Pd

分子量
715.88

灵敏度
Ambient temperatures.

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

750190

Sigma-Aldrich

Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)

95%

904.97元/1 G; 3783.45元/5 G;

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基本信息

经验(实验)分子式	C₃₆H₂₈Cl₂OP₂Pd
分子量	715.88
MDL编号	MFCD09953446
PubChem化学物质编号	329766057
NACRES	NA.22

产品性质

质量水平	100
测定	95%
mp	243-250 ℃
储存温度	2-8℃
SMILES string	Cl[Pd]Cl.O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6
InChI	1S/C36H28OP2.2ClH.Pd/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32;;;/h1-28H;2*1H;/q;;;+2/p-2
InChI key	VYOUBMJFTDMKRR-UHFFFAOYSA-L

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable