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CAS: 2049086-37-3
分子式: C39H42ClF2FeNNiP2
分子量: 784.8
中文名称: 
氯(4-氰基苯基)(R)-1-[(S)-2-(双(4-氟苯基)二茂铁膦基]乙基(二叔丁基膦基)镍(ii)
英文名称: 
chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(ii)
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货号品牌产品名称规格包装、参考价格详情
C990050MACKLIN氯(4-氰基苯基)[(R)-1-[(S)-2-[双(4-氟苯基]膦基]二茂铁基]乙基二-叔-丁基膦]镍(II)≥95%763元/100mg;   展开
储存:室温, 密封, 惰性气体
状态:固体
28-0178StremChloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)1215元/100mg;   4530元/500mg;   展开

Technical Notes:

1. Versatile air-stable low cost nickel catalyst alte rnative to palladium for carbon- carbon and carbon- heteroatom cross-coupling reactions .

2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines

3. Used in monoarylation experiments using comme rcially available ammonia gas, ammonium salts or ammonia stock solutions

4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hyd rochloride salts 3

References:

1.Org. Process Res. Dev., 2015, 19, 1936.

2.Angew. Chem, Int. Ed. 2015, 54, 37 73.

3.Angew. Chem, Int. Ed. 2015, 54, 3768.

900941Sigma-AldrichChloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)≥95%1714.04元/250 MG;   展开

产品说明

应用

Amination of functionalized aryl chlorides with ammonia and ammonium salts.

基本信息

经验(实验)分子式C39H42ClF2FeNNiP2
分子量774.69

产品性质

质量水平100
测定≥95%
形式powder or solid
reaction suitabilitycore: nickel
reagent type: catalyst
SMILES stringCC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=C(F)C=C2)C3=CC=C(F)C=C3.Cl[Ni]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]

安全信息

象形图GHS07GHS08GHS09
警示用语:Warning
危险声明H315 - H361d - H411
预防措施声明P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
危险分类Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
储存分类代码4.1B - Flammable solid hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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