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CAS: 2049086-36-2
分子式: C43H48ClFeNNiP2
分子量: 790.79
中文名称: 
氯(4-氰基苯基)(R)-1-[(S)-2-(二环己基膦)二茂铁]乙基(二苯基膦)镍(ii)
英文名称: 
chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (diphenylphosphine)}nickel(ii)
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C994347MACKLIN氯(4-氰基苯基){(R)-1-[(S)-2-(二环己基膦基)二茂铁基]乙基(二苯基膦)}镍(II)≥95%452元/50mg;   展开
储存:室温, 密封, 干燥, 惰性气体
状态:固体
28-0175StremChloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (diphenylphosphine)}nickel(II)1215元/100mg;   4530元/500mg;   展开

Technical Notes:

1. Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbon- heteroatom cross-coupling reactions.

2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryI amines

3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions

4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts 3

900942Sigma-AldrichChloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II)≥95%1817.8元/250 MG;   展开

产品说明

应用

Amination of aryl chlorides with ammonium salts.

其他说明

Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts
Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

基本信息

经验(实验)分子式C43H48ClFeNNiP2
分子量790.79

产品性质

质量水平100
测定≥95%
形式powder or solid
reaction suitabilitycore: nickel
reagent type: catalyst
SMILES stringC[Ni+]C1=CC=C(C#N)C=C1.[C]2(CP(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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