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CAS: 2049086-35-1
分子式: C43H60ClFeNNiP2
分子量: 813
中文名称: 
氯(4-氰基苯基)(R)-1-[(S)-2-(二环己基膦)二茂铁]乙基(二环己基膦)镍(ii)
英文名称: 
chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(ii)
推荐供应商
货号品牌产品名称规格包装、参考价格
C984952MACKLIN氯(4-氰基苯基)[(R)-1-[(S)-2-(二环己基膦基)二茂铁基]乙基二环已基膦]镍(II)1815元/250mg;   咨询
储存:室温, 密封, 惰性气体
状态:固体
28-0172StremChloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)1215元/100mg;   4530元/500mg;   咨询

Technical Notes:

1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbon- heteroatom cross-coupling reactions .

2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines

3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions

4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts

References:

1Org.Process Res. Dev., 2015, 19, 1936.

2.Angew. Chem, Int. Ed., 2015, 54, 3773.

3.Angew. Chem, Int. Ed., 2015, 54, 3768.

900943Sigma-AldrichChloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)1815.04元/250 MG;   咨询

产品说明

应用

Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.

其他说明

Nickel-Catalyzed Monoarylation of Ammonia
Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

基本信息

经验(实验)分子式C43H60ClFeNNiP2
分子量802.88

产品性质

质量水平100
形式powder or solid
reaction suitabilitycore: nickel
reagent type: catalyst
reaction type: Asymmetric synthesis
SMILES stringCl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]

安全信息

象形图GHS07GHS08GHS09
警示用语:Warning
危险声明H315 - H361d - H411
预防措施声明P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
危险分类Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
储存分类代码4.1B - Flammable solid hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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