CAS 2049086-34-0; 氯(4-氰基苯基)(R)-1-[(S)-2-(二苯基膦基)二茂铁]乙基(二叔丁基)膦镍(ii); chloro(4-cyanophenyl){(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl(di-t-butyl)phosphine} nickel(ii)

位置：首页 > 资料中心 > 化工字典 > 2049086-34-0

CAS:

2049086-34-0

分子式:

C₃₉H₄₄ClFeNNiP₂

分子量:

738.71

中文名称:

氯(4-氰基苯基)(R)-1-[(S)-2-(二苯基膦基)二茂铁]乙基(二叔丁基)膦镍(ii)

英文名称:

chloro(4-cyanophenyl){(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl(di-t-butyl)phosphine} nickel(ii)

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

C994346

MACKLIN

氯(4-氰基苯基)[(R)-1-[(S)-2-(二苯基膦基)二茂铁基]乙基二叔丁基膦]镍(II)

≥95%

451元/50mg;

咨询

储存：室温, 密封, 惰性气体
状态：固体

28-0170

Strem

Chloro(4-cyanophenyl){(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl(di-t-butyl)phosphine} nickel(II)

1215元/100mg; 4530元/500mg;

咨询

Technical Notes:

1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbon- heteroatom cross-coupling reactions .

2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines

3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions

4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts

References:

1Org.Process Res. Dev., 2015, 19, 1936.

2.Angew. Chem, Int. Ed., 2015, 54, 3773.

3.Angew. Chem, Int. Ed., 2015, 54, 3768.

900944

Sigma-Aldrich

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II)

≥95%

1815.04元/250 MG;

咨询

产品说明

应用

Amination of aryl chlorides with ammonia.

其他说明

Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts
Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

基本信息

经验(实验)分子式	C₃₉H₄₄ClFeNNiP₂
分子量	738.71

产品性质

质量水平	100
测定	≥95%
形式	powder or solid
reaction suitability	core: nickel reagent type: catalyst reaction type: Asymmetric synthesis
SMILES string	CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=CC=C2)C3=CC=CC=C3.[Ni+2]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H361d - H411
预防措施声明	P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
危险分类	Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

CAS号首数字顺序排列： 1 2 3 4 5 6 7 8 9