| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| S742941 | MACKLIN | (|S|)-(+)-α-甲氧基-α-(三氟甲基)苯乙酰氯 | Standard for GC, ≥99.7%(GC) | 3390元/50mg; | 咨询 |
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| S813730 | MACKLIN | (|S|)-(+)-α-甲氧基-α-(三氟甲基)苯乙酰氯 | 99% | 339元/50mg; 598元/100mg; 1224元/250mg; 2956元/1g; | 咨询 |
储存：-20°C,干燥 状态：无色到浅黄色液体 折射率：n20/D 1.47(lit.) |
| M1103 | TCI | (S)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl Chloride [for Determination of the optical purity of Alcohols and Amines] | >98.0%(GC)(T) | 1080元/100MG; 4390元/1G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC)(T) | | 分子式/分子量 | C10H8ClF3O2 = 252.62 | | 外观与形状(20℃) | 液体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (分解),加热 | | Reaxys-RN | 3591564 | | PubChem物质ID | 87573069 | | Merck Index (14) | 6280 | | MDL编号 | MFCD00067105 |
技术规格 | Appearance | Colorless to Almost colorless clear liquid | | Purity(GC) | min. 98.0 % | | Optical purity(GC) | min. 99.0 ee% | | Functionality test | to pass test |
物性(参考值) | 沸点 | 99 ℃/12 mmHg | | 闪点 | 89 ℃ | | 比重 | 1.35 | | 比旋光度 [α]D | 149° (C=2,Toluene) | | 折射率 | 1.47 |
安全信息 | 图形或危害标志 |  | | 信号词 | 危险 | | 危险性说明 | H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
H290 : 可能腐蚀金属。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物，防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。
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运输信息 | UN编号 | UN3265 | | 类别 | 8 | | 包装类别 | III | | 监管条件代码(*) | |
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| 191106 | J&K | (S)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride | 99% | 279元/50MG; 1114元/250MG; 3601元/1G; | 咨询 |
基本信息 | 分子式 | C10H8ClF3O2 | | 分子量 | 252.62 | | 沸点 | 68-72 | | 闪点 | 90 | | 密度 | 1.35 | | 折光率(n20D) | 1.4680-1.4700 | | MDL编码 | MFCD00067105 | | Beilstein | 3591562 | | Merck | 14,6280 | | 存储条件 | Store at 0℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H314 | | 防范说明 | P280
P305+P351+P338
P310 | | UN号码 | 3265 | | 危险分类 | 8 | | 包装等级 | II | | WGK | 3 | | TSCA | 否 |
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| L14332 | Alfa Aesar | (S)-(+)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetyl chloride | 98+% | 604元/50mg; 2319元/250mg; 6532元/1g; | 咨询 |
应用
(S)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride is used in the preparation of natural products and pheromones. It is also employed as a derivatization enantiomeric purity reagent used for the determination of enantiomeric purity of alcohol and amines by gas chromatography. 备注
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents, strong acids and bases. 基本信息 MDL
MFCD00067105 分子式
C10H8ClF3O2 分子量
252.62 沸点
213-214° 闪点
89°(192°F) 密度
1.353 折射率
1.4690 灵敏度
Store at -20°C. Moisture Sensitive. Store under Nitrogen. 形态
Liquid 溶解性
Slightly miscible with water. Beilstein
3591564 Merck
14,6280 GHS危害和防范说明 GHS符号
Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
8 包装组
II 危险类别
34
Causes burns. 安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
 TSCA
否 |
| C26411 | Alfa Aesar | (S)-(+)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetyl chloride | 99% | 1843元/250mg; 6048元/1g; | 咨询 |
基本信息 Ref#
26411 MDL
67105 分子式
C10 H8 Cl F3 O2 分子量
252.62 闪点
90 密度
1.34 形态
Liquid, Packaged under argon 安全信息 危险等级
8 包装组
II |
| 369675 | Sigma-Aldrich | (S)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride | 99% | 618.62元/50 MG; 1455.38元/250 MG; | 咨询 |
产品说明 一般描述 (S)-(+)-α-甲氧基-α-三氟甲基苯乙酰氯通常用作 Mosher 酯分析和 Mosher 酰胺分析中的衍生剂，这是基于核磁共振法分别测定仲醇和胺类化合物中手性碳中心绝对构型的方法。 包装 50, 250 mg in glass bottle
无底玻璃瓶。内含物装在插入的融合锥内。 应用 用于合成天然产物和信息素。 其他说明 doi:10.1038/nprot.2007.354 基本信息 | 线性分子式 | C6H5C(OCH3)(CF3)COCl | | 分子量 | 252.62 | | Beilstein | 3591562 | | MDL编号 | MFCD00067105 | | PubChem化学物质编号 | 24863007 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 99% | | 光学纯度 | ee: 98% (GLC) | | 折射率 | n20/D 1.469 (lit.) | | bp | 213-214 ℃ (lit.) | | 密度 | 1.35 g/mL at 25 ℃ (lit.) | | 储存温度 | −20℃ | | SMILES string | CO[C@@](C(Cl)=O)(c1ccccc1)C(F)(F)F | | InChI | 1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m1/s1 | | InChI key | PAORVUMOXXAMPL-SECBINFHSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H314 | | 预防措施声明 | P280 - P305 + P351 + P338 - P310 | | 危险分类 | Skin Corr. 1B | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 3 | | 闪点(F) | 192.2 °F - closed cup | | 闪点(C) | 89 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 65365 | Supelco | (S)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride | for chiral derivatization, LiChropur™, ≥99.0% | 2022.75元/100 MG; 7999.01元/500 MG; | 咨询 |
产品说明 应用 立体甲醇碳绝对构型的检测； doi:10.1038/nprot.2007.354 包装 无底玻璃瓶。内含物在插入的融合锥体内。 推荐产品 探索最适于 HPLC 或 LC-MS 分析的 LiChropur 试剂 法律信息 LiChropur is a trademark of Merck KGaA, Darmstadt, Germany 基本信息 | 线性分子式 | C6H5C(OCH3)(CF3)COCl | | 分子量 | 252.62 | | Beilstein | 3591562 | | MDL编号 | MFCD00067105 | | PubChem化学物质编号 | 329760057 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 等级 | for chiral derivatization | | 测定 | ≥99.0% (AT)
≥99.0% | | 旋光性 | [α]20/D +137±2°, c = 6.4% in carbon tetrachloride | | 光学纯度 | enantiomeric ratio: ≥99.5:0.5 (GC) | | 质量 | LiChropur™ | | technique(s) | HPLC: suitable | | 折射率 | n20/D 1.469 (lit.)
n20/D 1.469 | | bp | 213-214 ℃ (lit.) | | 密度 | 1.35 g/mL at 25 ℃ (lit.) | | 运输 | wet ice | | 储存温度 | −20℃ | | SMILES string | CO[C@@](C(Cl)=O)(c1ccccc1)C(F)(F)F | | InChI | 1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m1/s1 | | InChI key | PAORVUMOXXAMPL-SECBINFHSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H314 | | 预防措施声明 | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 | | 危险分类 | Skin Corr. 1B | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 3 | | 闪点(F) | 192.2 °F - closed cup | | 闪点(C) | 89 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 009427 | Fluorochem | (S)-(+)-a-Methoxy-a-trifluoromethylphenylacetyl chloride | 98% | 1100元/100mg; 5764元/1g; | 咨询 |
基本信息 | CAS Number | 20445-33-4 | | MDL Number | MFCD00067105 | | Boiling Point | 213-214℃ | | Density | 1.353 |
安全信息 | 图形或危害标志 |   | | 危险性说明 | H301: Toxic if swallowed.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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