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CAS: 201802-67-7
分子式: C18H16BNO2
分子量: 289.14
熔点: 110-115 ℃(lit.)
英文名称: 
4-(Diphenylamino)phenylboronic acid
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D808065MACKLIN4-(二苯基胺基)苯硼酸98%30元/1g;   70元/5g;   330元/25g;   1234元/100g;   展开
储存:室温
状态:白色到灰白色粉末,晶体和/或块状
D3537TCI4-(Diphenylamino)phenylboronic Acid (contains varying amounts of Anhydride)120元/1G;   390元/5G;   展开

基本信息

分子式/分子量C18H16BNO2 = 289.14
外观与形状(20℃)固体
Reaxys-RN9409074
PubChem物质ID87560019
MDL编号MFCD06798117

技术规格

AppearanceWhite to Dark green powder to crystal
Purity(Neutralization titration)97.0 to 108.0 %

物性(参考值)

熔点228 ℃
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
802106J&K4-(Diphenylamino)phenylboronic acid98%326元/1G;   1117元/5G;   展开

基本信息

分子式C18H16BNO2
分子量289.14
熔点110-115
MDL编码MFCD06798117
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
H52902Alfa Aesar4-(Diphenylamino)benzeneboronic acid98%1214元/250mg;   3888元/1g;   展开

基本信息

MDL
MFCD06798117

分子式
C18H16BNO2

分子量
289.14

熔点
110-115°

形态
Solid

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

647292Sigma-Aldrich4-(Diphenylamino)phenylboronic acid≥95%432.59元/1 G;   2054.81元/5 G;   展开

产品说明

应用

试剂用于

  • 强多光子激发的蓝色光致发光和梯型低聚(对亚苯基)激光
  • Suzuki 偶联反应
  • 无配体的铃木反应

试剂用于制备
  • 推拉式芳基乙烯基噻嗪发色团
  • 含有三苯胺官能团的基于苯并噻二唑的荧光团
  • 用于电致发光器件的蓝光发射和空穴传输材料
  • 用二甲基甲酰基侧向取代的对四联苯,用作固态蓝光发射器
  • 用于染料敏化太阳能电池的高效敏化剂
  • 用于单层白色聚合物 OLED 的 Prange 电致发光材料
  • Eeep-blue 有机电致发光器件(OLED)
  • 有机光伏电池的配体

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C18H16BNO2
分子量289.14
MDL编号MFCD06798117
PubChem化学物质编号24883523
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式powder
mp110-115 ℃ (lit.)
SMILES stringOB(O)c1ccc(cc1)N(c2ccccc2)c3ccccc3
InChI1S/C18H16BNO2/c21-19(22)15-11-13-18(14-12-15)20(16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14,21-22H
InChI keyTWWQCBRELPOMER-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
989440Amethyst4-(Diphenylamino)phenylboronic acid98%, 用于合成125元/1G;   434元/5G;   717元/25G;   2469元/100G;   展开

基本信息

分子式C18H16BNO2
分子量289.14
熔点228
MDL编码MFCD06798117
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
049900Fluorochem4-(Diphenylamino)phenylboronic acid98%462元/1g;   1342元/5g;   2244元/10g;   4290元/25g;   展开

基本信息

CAS Number201802-67-7
MDL NumberMFCD06798117
Melting Point110-115℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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