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CAS: 20099-89-2
分子式: C9H6BrNO
分子量: 224.05
熔点: 92-96℃
中文名称: 
4-溴乙酰基苯腈
4-氰基苯甲酰溴
英文名称: 
cyanophenacylbromide
2-Bromo-4'-cyanoacetophenone
4-(Bromoacetyl)benzonitrile
4-cyanophenacyl bromide
推荐供应商
货号品牌产品名称规格包装、参考价格
B803923MACKLIN2-溴-4'-氰基苯乙酮98.0%128元/5g;   210元/10g;   370元/25g;   1300元/100g;   4680元/500g;   咨询
储存:室温,避光
状态:白色到浅黄色粉末或晶体
C1348TCI4-Cyanophenacyl Bromide>96.0%(GC)(T)420元/5G;   1205元/25G;   咨询

基本信息

纯度/分析方法>96.0%(GC)(T)
分子式/分子量C9H6BrNO = 224.06
外观与形状(20℃)固体
Reaxys-RN2087648
PubChem物质ID87566360
MDL编号MFCD00052931

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(GC)min. 96.0 %
Purity(Argentometric Titration)min. 96.0 %
Melting point92.0 to 94.0 ℃

物性(参考值)

熔点93 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H314 : 造成严重皮肤灼伤和眼损伤。
H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

运输信息

UN编号UN2923
类别8 / 6.1
包装类别 III
监管条件代码(*)
281958J&K2-Bromo-4′-cyanoacetophenone97%247元/5G;   825元/25G;   咨询

基本信息

分子式C9H6BrNO
分子量224.05
熔点92-96
MDL编码MFCD00052931
Beilstein2087648

安全信息

图形或危害标志
提示语Danger
危险说明H302
H312
H314
H332
防范说明P280
P305+P351+P338
P310
UN号码2928
危险分类6.1
次要危险性8
包装等级II
WGK3
B25382Alfa Aesar4-(Bromoacetyl)benzonitrile97%985元/5g;   3141元/25g;   咨询

基本信息

MDL
MFCD00052931

分子式
C9H6BrNO

分子量
224.06

熔点
91-96°

形态
Powder

Beilstein
2087648

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332-H314-H318
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
20/21/22-34
Harmful by inhalation, in contact with skin and if swallowed.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C36536Alfa Aesar2-Bromo-4'-cyanoacetophenone97%809元/5g;   2689元/25g;   咨询

基本信息

Ref#
36536

MDL
52931

分子式
C9 H6 Br N O

分子量
224.06

形态
White to pale brown powder

安全信息

危险等级
6.1

包装组
II

539392Sigma-Aldrich2-Bromo-4′-cyanoacetophenone96%421.46元/5 G;   821.56元/25 G;   咨询

产品说明

一般描述

2-Bromo-4′-cyanoacetophenone can be synthesized from ethylbenzene via aerobic photooxidation using aqueous HBr.

应用

2-Bromo-4′-cyanoacetophenone may be used to synthesize:

  • 3-acylindolizines
  • (2R,3R)-3-[4-(4-cyanophenyl)thiazol-2-yl]-2-(2,4-difluorophenyl)-1-(1H-1,2,4-triazol-1-yl)-2-butanol
  • 1-[2-(4-cyanophenyl)-2-oxoethyl]-1,10-phenanthrolinium bromide

包装

5, 25 g in glass bottle

基本信息

线性分子式BrCH2COC6H4CN
分子量224.05
MDL编号MFCD00052931
PubChem化学物质编号24878394
NACRESNA.22

产品性质

质量水平100
测定96%
mp92-96 ℃ (lit.)
SMILES stringBrCC(=O)c1ccc(cc1)C#N
InChI1S/C9H6BrNO/c10-5-9(12)8-3-1-7(6-11)2-4-8/h1-4H,5H2
InChI keyLJANCPRIUMHGJE-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 + H312 + H332 - H314
预防措施声明P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
018079Fluorochem4-(2-Bromoacetyl)benzonitrile97%220元/1g;   726元/25g;   2112元/100g;   4136元/250g;   咨询

基本信息

CAS Number20099-89-2
MDL NumberMFCD00052931
Boiling Point342.4℃
Melting Point91-96℃
Density1.56

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.
防范说明 P260: Do not breathe
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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