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CAS: 1973375-72-2
分子式: C36H16F22IrN4P
分子量: 1145.6899
熔点: >300 °C
中文名称: 
[5,5'-双(三氟甲基)-2,2'-联吡啶-κn,κn]双[3,5-二氟-2- [5-(三氟甲基)-2-吡啶基-κn]苯基]六氟磷酸铱
[5,5'-bis(trifluoromethyl)-2,2'-bipyridine-κn,κn]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κn]phenyl] iridium hexafluorophosphate
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货号品牌产品名称规格包装、参考价格详情
B919265MACKLIN[5,5'-双(三氟甲基)-2,2'-联吡啶-κN,κN]双[3,5-二氟-2-[5-(三氟甲基)-2-吡啶基-κN]苯基]铱六氟磷酸盐98%192元/50mg;   801元/250mg;   2200元/500g;   3203元/1g;   展开
储存:2-8°C,惰性气体,密封
状态:浅黄色到黄色粉末或晶体
77-0370Strem[5,5'-Bis(trifluoromethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl] iridium hexafluorophosphate98%1500元/50mg;   3735元/250mg;   展开

Technical Notes:

1.Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

2.Intermolecular anti- Markovnikov hydroamination of unactivated alkenes with sulfonamides enabled by proton-coupled electron transfer.

References:

1.Nature.2016, 539, 268.

2. J. Am. Chem. Soc., 2018, 140, 741.

Y24026Alfa Aesar([Ir(dF(CF3ppy)2)(5,5'-CF3-bpy)]PF61786元/100mg;   展开

基本信息

分子量
1145.69

908568Sigma-Aldrich[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6≥95%1436.5元/100 MG;   3792.81元/500 MG;   展开

产品说明

应用

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.

其他说明

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation

基本信息

经验(实验)分子式C36H16F22IrN4P
分子量1145.69

产品性质

测定≥95%
形式powder or crystals
reaction suitabilityreaction type: Photocatalysis
reagent type: catalyst
mp>300 ℃
photocatalyst activation460 nm

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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